Abbas F. Gharib, Jan Ibrahim Ismael, Radhwan K. Alatroshe, Hawazen N. Farhan, Mohamed I. Abdel-Fattah, John D. Pigott
{"title":"伊拉克美索不达米亚前深盆地中侏罗纪-下白垩统演替的有机质特征和碳氢化合物生成潜力","authors":"Abbas F. Gharib, Jan Ibrahim Ismael, Radhwan K. Alatroshe, Hawazen N. Farhan, Mohamed I. Abdel-Fattah, John D. Pigott","doi":"10.1007/s00531-024-02434-6","DOIUrl":null,"url":null,"abstract":"<p>The Jurassic–Cretaceous source rocks and their exploratory operations in the Mesopotamian Foredeep Basin are limited, and the origins of recovered hydrocarbons have not been comprehensively investigated. Comprehensive geochemical analyses and 1-D basin models were performed on the Middle Jurassic–Lower Cretaceous succession. Additionally, geochemical analyses of eight crude oils from Upper Cretaceous reservoirs were used to evaluate the conventional petroleum resource potential and petroleum exploration and development. The total organic carbon (TOC) and Rock–Eval results reveal the Middle Jurassic–Lower Cretaceous succession to be characterized by fair to excellent source rock potential and consists mainly of Types II/III and III kerogens. Consequently, the Middle Jurassic–Lower Cretaceous succession can generate both oil and gas, with high oil generation potential. The dominance of such kerogen is confirmed by the substantial lipids derived from phytoplanktonic, bacterial, and algal organic matter, as indicated by biomarker compositions. Furthermore, biomarker parameters and isotopic compositions of oil samples provide evidence of a genetic link between the Middle Jurassic–Lower Cretaceous source rocks and crude oils. The data suggest that the non-biodegraded oils were generated from mature marine source rocks deposited under reducing conditions. One-dimensional basin models show that the oil generation from the organic matter-rich intervals within the Sargelu, Najmah/Naokelekan, and Gotina formations started during the Upper Cretaceous and continued into the Miocene (83–21 Ma) at low maturity levels (EASY%<i>R</i><sub>o</sub> > 0.50%). Oil expulsion from the Sargelu, Najmah/Naokelekan, and Gotina formations has taken place since the Miocene until now (21–0 Ma) with higher conversion ratios (%TR > 50%) and migrating through vertical pathways provided by faults and being trapped within Upper Cretaceous reservoirs.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>","PeriodicalId":13845,"journal":{"name":"International Journal of Earth Sciences","volume":"37 1","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Organic matter characteristics and hydrocarbon generation potential of the Middle Jurassic–Lower Cretaceous succession in the Mesopotamian Foredeep Basin, Iraq\",\"authors\":\"Abbas F. Gharib, Jan Ibrahim Ismael, Radhwan K. Alatroshe, Hawazen N. Farhan, Mohamed I. Abdel-Fattah, John D. Pigott\",\"doi\":\"10.1007/s00531-024-02434-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The Jurassic–Cretaceous source rocks and their exploratory operations in the Mesopotamian Foredeep Basin are limited, and the origins of recovered hydrocarbons have not been comprehensively investigated. Comprehensive geochemical analyses and 1-D basin models were performed on the Middle Jurassic–Lower Cretaceous succession. Additionally, geochemical analyses of eight crude oils from Upper Cretaceous reservoirs were used to evaluate the conventional petroleum resource potential and petroleum exploration and development. The total organic carbon (TOC) and Rock–Eval results reveal the Middle Jurassic–Lower Cretaceous succession to be characterized by fair to excellent source rock potential and consists mainly of Types II/III and III kerogens. Consequently, the Middle Jurassic–Lower Cretaceous succession can generate both oil and gas, with high oil generation potential. The dominance of such kerogen is confirmed by the substantial lipids derived from phytoplanktonic, bacterial, and algal organic matter, as indicated by biomarker compositions. Furthermore, biomarker parameters and isotopic compositions of oil samples provide evidence of a genetic link between the Middle Jurassic–Lower Cretaceous source rocks and crude oils. The data suggest that the non-biodegraded oils were generated from mature marine source rocks deposited under reducing conditions. One-dimensional basin models show that the oil generation from the organic matter-rich intervals within the Sargelu, Najmah/Naokelekan, and Gotina formations started during the Upper Cretaceous and continued into the Miocene (83–21 Ma) at low maturity levels (EASY%<i>R</i><sub>o</sub> > 0.50%). Oil expulsion from the Sargelu, Najmah/Naokelekan, and Gotina formations has taken place since the Miocene until now (21–0 Ma) with higher conversion ratios (%TR > 50%) and migrating through vertical pathways provided by faults and being trapped within Upper Cretaceous reservoirs.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical abstract</h3>\",\"PeriodicalId\":13845,\"journal\":{\"name\":\"International Journal of Earth Sciences\",\"volume\":\"37 1\",\"pages\":\"\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-07-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Earth Sciences\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://doi.org/10.1007/s00531-024-02434-6\",\"RegionNum\":3,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"GEOSCIENCES, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Earth Sciences","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.1007/s00531-024-02434-6","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
美索不达米亚前深盆地的侏罗纪-白垩纪源岩及其勘探作业十分有限,尚未对回收碳氢化合物的来源进行全面研究。对中侏罗世-下白垩统演替进行了全面的地球化学分析,并建立了一维盆地模型。此外,还对来自上白垩统储层的八种原油进行了地球化学分析,以评估常规石油资源潜力和石油勘探开发。总有机碳(TOC)和岩石评价结果显示,中侏罗世-下白垩统演替的源岩潜力从一般到优秀不等,主要由 II/III 型和 III 型角砾岩组成。因此,中侏罗世-下白垩统演替既能生成石油,也能生成天然气,具有很高的石油生成潜力。生物标志物成分显示,大量脂质来自浮游植物、细菌和藻类有机物,这证实了此类角质的主导地位。此外,石油样本的生物标志物参数和同位素组成也证明了中侏罗世-下白垩统源岩与原油之间的遗传联系。数据表明,非生物降解油是由在还原条件下沉积的成熟海相源岩生成的。一维盆地模型显示,石油从上白垩统的萨尔格鲁、纳杰马/诺克勒坎和戈蒂纳地层中富含有机质的层间开始生成,并以较低的成熟度(EASY%Ro > 0.50%)持续到中新世(83-21Ma)。石油从 Sargelu、Najmah/Naokelekan 和 Gotina 地层排出的时间始于中新世至今(21-0 Ma),转换率较高(%TR > 50%),通过断层提供的垂直路径迁移,并被困在上白垩统储层中。
Organic matter characteristics and hydrocarbon generation potential of the Middle Jurassic–Lower Cretaceous succession in the Mesopotamian Foredeep Basin, Iraq
The Jurassic–Cretaceous source rocks and their exploratory operations in the Mesopotamian Foredeep Basin are limited, and the origins of recovered hydrocarbons have not been comprehensively investigated. Comprehensive geochemical analyses and 1-D basin models were performed on the Middle Jurassic–Lower Cretaceous succession. Additionally, geochemical analyses of eight crude oils from Upper Cretaceous reservoirs were used to evaluate the conventional petroleum resource potential and petroleum exploration and development. The total organic carbon (TOC) and Rock–Eval results reveal the Middle Jurassic–Lower Cretaceous succession to be characterized by fair to excellent source rock potential and consists mainly of Types II/III and III kerogens. Consequently, the Middle Jurassic–Lower Cretaceous succession can generate both oil and gas, with high oil generation potential. The dominance of such kerogen is confirmed by the substantial lipids derived from phytoplanktonic, bacterial, and algal organic matter, as indicated by biomarker compositions. Furthermore, biomarker parameters and isotopic compositions of oil samples provide evidence of a genetic link between the Middle Jurassic–Lower Cretaceous source rocks and crude oils. The data suggest that the non-biodegraded oils were generated from mature marine source rocks deposited under reducing conditions. One-dimensional basin models show that the oil generation from the organic matter-rich intervals within the Sargelu, Najmah/Naokelekan, and Gotina formations started during the Upper Cretaceous and continued into the Miocene (83–21 Ma) at low maturity levels (EASY%Ro > 0.50%). Oil expulsion from the Sargelu, Najmah/Naokelekan, and Gotina formations has taken place since the Miocene until now (21–0 Ma) with higher conversion ratios (%TR > 50%) and migrating through vertical pathways provided by faults and being trapped within Upper Cretaceous reservoirs.
期刊介绍:
The International Journal of Earth Sciences publishes process-oriented original and review papers on the history of the earth, including
- Dynamics of the lithosphere
- Tectonics and volcanology
- Sedimentology
- Evolution of life
- Marine and continental ecosystems
- Global dynamics of physicochemical cycles
- Mineral deposits and hydrocarbons
- Surface processes.