基于多金属 MOF 的环境应用复合材料:金属中心与相互作用的协同作用。

IF 8 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Wei Wang, Bergoi Ibarlucea, Chuanhui Huang, Renhao Dong, Muhannad Al Aiti, Shirong Huang and Gianaurelio Cuniberti
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引用次数: 0

摘要

过去二十年来,环境问题对自然和人类的威胁不断升级,这凸显了解决环境污染物问题的紧迫性。金属有机框架(MOFs)已成为应对这些挑战的极有前途的材料。自 MOFs 开始流行以来,人们对其进行了广泛的研究,从设计和合成到广泛的应用,如环境修复、气体储存和分离、催化、传感器、生物医学和药物输送系统、能量储存和转换以及光电器件等。MOFs 具有多种优势特性,如比表面积大、孔隙率可调、孔隙结构多样、多通道设计和分子筛功能等,因此在环境应用方面特别具有吸引力。基于 MOF 的复合材料继承了 MOF 的优良特性,同时也表现出独特的物理化学特性和结构。定制 MOF 中的中心配位金属离子对其在环境应用中的适应性至关重要。尽管有关单金属、双金属和多金属 MOFs 的综述已经发表了很多,但很少有综述关注在环境污染物处理中基于 MOFs 的单金属、双金属和多金属中心复合材料。本综述针对这一空白,深入综述了基于 MOF 的复合材料的最新进展,强调了它们在有害气体传感、电磁波吸收 (EMWA) 以及水环境和大气环境中污染物降解方面的应用,并强调了存在的金属中心的数量和类型的重要性。此外,还总结了 MOF 的各种类别。基于 MOF 的复合材料在应对环境挑战方面大有可为,本综述从一个清晰而有价值的角度阐述了它们在环境应用中的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Multi-metallic MOF based composites for environmental applications: synergizing metal centers and interactions

Multi-metallic MOF based composites for environmental applications: synergizing metal centers and interactions

Multi-metallic MOF based composites for environmental applications: synergizing metal centers and interactions

The escalating threat of environmental issues to both nature and humanity over the past two decades underscores the urgency of addressing environmental pollutants. Metal–organic frameworks (MOFs) have emerged as highly promising materials for tackling these challenges. Since their rise in popularity, extensive research has been conducted on MOFs, spanning from design and synthesis to a wide array of applications, such as environmental remediation, gas storage and separation, catalysis, sensors, biomedical and drug delivery systems, energy storage and conversion, and optoelectronic devices, etc. MOFs possess a multitude of advantageous properties such as large specific surface area, tunable porosity, diverse pore structures, multi-channel design, and molecular sieve capabilities, etc., making them particularly attractive for environmental applications. MOF-based composites inherit the excellent properties of MOFs and also exhibit unique physicochemical properties and structures. The tailoring of central coordinated metal ions in MOFs is critical for their adaptability in environmental applications. Although many reviews on monometallic, bimetallic, and polymetallic MOFs have been published, few reviews focusing on MOF-based composites with monometallic, bimetallic, and multi-metallic centers in the context of environmental pollutant treatment have been reported. This review addresses this gap by providing an in-depth overview of the recent progress in MOF-based composites, emphasizing their applications in hazardous gas sensing, electromagnetic wave absorption (EMWA), and pollutant degradation in both aqueous and atmospheric environments and highlighting the importance of the number and type of metal centers present. Additionally, the various categories of MOFs are summarized. MOF-based composites demonstrate significant promise in addressing environmental challenges, and this review provides a clear and valuable perspective on their potential in environmental applications.

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来源期刊
Nanoscale Horizons
Nanoscale Horizons Materials Science-General Materials Science
CiteScore
16.30
自引率
1.00%
发文量
141
期刊介绍: Nanoscale Horizons stands out as a premier journal for publishing exceptionally high-quality and innovative nanoscience and nanotechnology. The emphasis lies on original research that introduces a new concept or a novel perspective (a conceptual advance), prioritizing this over reporting technological improvements. Nevertheless, outstanding articles showcasing truly groundbreaking developments, including record-breaking performance, may also find a place in the journal. Published work must be of substantial general interest to our broad and diverse readership across the nanoscience and nanotechnology community.
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