从废塑料瓶中提取的丝光亚麻-聚(聚乙烯醇+丙烯酸)增强聚酯树脂:动态力学分析和耐化学-热性能

IF 2.4 3区 化学 Q3 POLYMER SCIENCE
Himani Sharma, Susmriti Dolui, Saksham, Divyansh Saini, Raman Bedi, Balbir Singh Kaith
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引用次数: 0

摘要

本研究旨在制造一种用丝光亚麻-聚(聚乙烯醇胆+丙烯酸)共聚物增强的聚酯复合材料。此外,还利用动态机械分析(DMA)技术对机械性能进行了比较研究,以确定生亚麻(rFlax)和丝光亚麻(mFlax)对基体的增强作用,从而将这种复合材料用于防水壁板、橱柜和家具面板。聚酯树脂取自废塑料瓶。聚乙烯醇(PVA)和丙烯酸(AA)的二元乙烯基单体混合物被接枝共聚到亚麻上,接枝率达到 118.3%。接枝的 mFlax 具有更高的耐酸碱性、耐溶剂性和耐热性。研究了所制备复合材料的不同机械参数,如储存模量、损失模量和阻尼。mFlax-g 聚(PVA + AA)增强复合材料显示出更高的存储模量(E')和更高的 Tanδ 值,这表明其具有优异的阻尼特性。此外,还观察到较高的玻璃化转变温度,热研究进一步证实了这一点。本研究的新颖之处在于采用了变废为宝的方法,在制备复合材料时使用了经过化学改性的纺织废料和回收塑料树脂。通过 DMA 获得的机械性能表明,用化学改性亚麻增强的复合材料具有更好的储存模量、损失模量和阻尼性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Mercerized flax-g-poly(polyvinyl alcohol + acrylic acid) reinforced polyester resin derived from waste plastic bottles: dynamic mechanical analysis and chemical-thermal resistance

Mercerized flax-g-poly(polyvinyl alcohol + acrylic acid) reinforced polyester resin derived from waste plastic bottles: dynamic mechanical analysis and chemical-thermal resistance

The aim of present work is to fabricate a polyester composite reinforced with mercerized flax-g-poly(polyvinyl alchol + acrylic acid) copolymer. In addition, a comparative study of mechanical properties using dynamic mechanical analysis (DMA) technique was made as a function of reinforcement of matrix with raw flax (rFlax) and mercerized flax (mFlax) in order to be able to use such composites in water resistant wall panelling, cupboards and furniture tops. Polyester resin was derived from waste plastic bottles. Binary vinyl monomer mixture of polyvinyl alcohol (PVA) and acrylic acid (AA) was graft copolymerized onto mFlax and a graft yield of 118.3% was obtained. Grafted mFlax showed higher acid–base, solvent and thermal resistance. Composites prepared were studied for different mechanical parameters like storage modulus, loss modulus and damping. The mFlax-g-poly(PVA + AA) reinforced composite showed higher storage modulus (E’) and exhibited higher Tanδ value which indicated superior damping properties. A higher glass transition temperature was also observed, which was further supported by thermal studies. The novelty of the present work is the approach of waste to wealth, in which chemically modified textile waste and recycled plastic resins were used in the preparation of composites. The mechanical properties obtained through DMA showed that the composite reinforced with chemically modified flax had better storage modulus, loss modulus and damping properties.

Graphical abstract

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来源期刊
Iranian Polymer Journal
Iranian Polymer Journal 化学-高分子科学
CiteScore
4.90
自引率
9.70%
发文量
107
审稿时长
2.8 months
期刊介绍: Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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