定向基团辅助过渡金属催化邻碳硼烷的选择性 BH 功能化

Synthesis Pub Date : 2024-06-11 DOI:10.1055/a-2343-0780
Jie Zhang, Zuowei Xie
{"title":"定向基团辅助过渡金属催化邻碳硼烷的选择性 BH 功能化","authors":"Jie Zhang, Zuowei Xie","doi":"10.1055/a-2343-0780","DOIUrl":null,"url":null,"abstract":"Carboranes are a type of molecular clusters consisting of carbon, hydrogen and boron atoms. They possess unique characteristics such as three-dimensional aromaticity, icosahedral geometry, and robustness. Functionalized carboranes have been utilized in various fields including medicine, materials, and organometallic/coordination chemistry. In this context, selective functionalization of o-carboranes has received tremendous attention, specifically in the regio- and enantio-selective modification of the ten chemically similar BH vertices within the carborane cage. In recent years, significant progress has been made in catalytic vertex-specific BH functionalization, as well as achieving enantioselective functionalization of the cage BH. This review provides an overview of the recent advancements in this research field.","PeriodicalId":501298,"journal":{"name":"Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Directing Group Assisted Transition Metal Catalyzed Selective BH Functionalization of o-Carboranes\",\"authors\":\"Jie Zhang, Zuowei Xie\",\"doi\":\"10.1055/a-2343-0780\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Carboranes are a type of molecular clusters consisting of carbon, hydrogen and boron atoms. They possess unique characteristics such as three-dimensional aromaticity, icosahedral geometry, and robustness. Functionalized carboranes have been utilized in various fields including medicine, materials, and organometallic/coordination chemistry. In this context, selective functionalization of o-carboranes has received tremendous attention, specifically in the regio- and enantio-selective modification of the ten chemically similar BH vertices within the carborane cage. In recent years, significant progress has been made in catalytic vertex-specific BH functionalization, as well as achieving enantioselective functionalization of the cage BH. This review provides an overview of the recent advancements in this research field.\",\"PeriodicalId\":501298,\"journal\":{\"name\":\"Synthesis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-06-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1055/a-2343-0780\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-2343-0780","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

硼烷是一种由碳、氢和硼原子组成的分子团簇。它们具有独特的特性,如三维芳香性、二十面体几何形状和坚固性。功能化碳硼烷已被应用于医药、材料和有机金属/配位化学等多个领域。在这方面,邻碳硼烷的选择性官能化受到了极大关注,特别是对碳硼烷笼内十个化学性质相似的 BH 顶点进行区域和对映选择性修饰。近年来,在催化顶点特异性 BH 功能化以及实现笼 BH 的对映选择性功能化方面取得了重大进展。本综述概述了这一研究领域的最新进展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Directing Group Assisted Transition Metal Catalyzed Selective BH Functionalization of o-Carboranes

Directing Group Assisted Transition Metal Catalyzed Selective BH Functionalization of o-Carboranes
Carboranes are a type of molecular clusters consisting of carbon, hydrogen and boron atoms. They possess unique characteristics such as three-dimensional aromaticity, icosahedral geometry, and robustness. Functionalized carboranes have been utilized in various fields including medicine, materials, and organometallic/coordination chemistry. In this context, selective functionalization of o-carboranes has received tremendous attention, specifically in the regio- and enantio-selective modification of the ten chemically similar BH vertices within the carborane cage. In recent years, significant progress has been made in catalytic vertex-specific BH functionalization, as well as achieving enantioselective functionalization of the cage BH. This review provides an overview of the recent advancements in this research field.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信