定向基团辅助过渡金属催化邻碳硼烷的选择性 BH 功能化

Synthesis Pub Date : 2024-06-11 DOI:10.1055/a-2343-0780
Jie Zhang, Zuowei Xie
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引用次数: 0

摘要

硼烷是一种由碳、氢和硼原子组成的分子团簇。它们具有独特的特性,如三维芳香性、二十面体几何形状和坚固性。功能化碳硼烷已被应用于医药、材料和有机金属/配位化学等多个领域。在这方面,邻碳硼烷的选择性官能化受到了极大关注,特别是对碳硼烷笼内十个化学性质相似的 BH 顶点进行区域和对映选择性修饰。近年来,在催化顶点特异性 BH 功能化以及实现笼 BH 的对映选择性功能化方面取得了重大进展。本综述概述了这一研究领域的最新进展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Directing Group Assisted Transition Metal Catalyzed Selective BH Functionalization of o-Carboranes

Directing Group Assisted Transition Metal Catalyzed Selective BH Functionalization of o-Carboranes
Carboranes are a type of molecular clusters consisting of carbon, hydrogen and boron atoms. They possess unique characteristics such as three-dimensional aromaticity, icosahedral geometry, and robustness. Functionalized carboranes have been utilized in various fields including medicine, materials, and organometallic/coordination chemistry. In this context, selective functionalization of o-carboranes has received tremendous attention, specifically in the regio- and enantio-selective modification of the ten chemically similar BH vertices within the carborane cage. In recent years, significant progress has been made in catalytic vertex-specific BH functionalization, as well as achieving enantioselective functionalization of the cage BH. This review provides an overview of the recent advancements in this research field.
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