环氧胺体系的时间-温度-转化（TTT）固化示意图

IF 1.8 4区工程技术 Q3 POLYMER SCIENCE

Macromolecular Theory and Simulations Pub Date : 2024-06-15 DOI:10.1002/mats.202400039

Claire Strasser, Elena Moukhina, Jürgen Hartmann

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引用次数: 0

摘要

为一种基于 DGEBA 的环氧树脂的固化反应绘制了时间-温度-转变（TTT）图。该图由以下部分组成：通过动态 DSC 测量进行的动力学分析；通过等温和动态流变测试确定的凝胶化曲线；以及通过温度调制动态 DSC 测量获得的玻璃化曲线。通过将等温测量结果与相应的计算曲线进行比较，验证了得出的图表。本文受版权保护。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Time–Temperature-Transformation (TTT) Cure Diagram of an Epoxy–Amine System

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Time–Temperature-Transformation (TTT) Cure Diagram of an Epoxy–Amine System

A time–temperature-transformation diagram is created for the curing reaction of a diglycidylether bisphenol A (DGEBA)-based epoxy resin. It results from a kinetic analysis performed by means of dynamical differential scanning calorimetry (DSC) measurements; a gelation curve determined with isothermal and dynamical rheological tests; and a vitrification curve obtained from temperature-modulated dynamic DSC measurements. The resulting diagram is validated by comparison of isothermal measurements with the corresponding calculated curves.

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来源期刊

Macromolecular Theory and Simulations 工程技术-高分子科学

CiteScore

3.00

自引率

14.30%

发文量

审稿时长

2 months

期刊介绍： Macromolecular Theory and Simulations is the only high-quality polymer science journal dedicated exclusively to theory and simulations, covering all aspects from macromolecular theory to advanced computer simulation techniques.