{"title":"环氧胺体系的时间-温度-转化(TTT)固化示意图","authors":"Claire Strasser, Elena Moukhina, Jürgen Hartmann","doi":"10.1002/mats.202400039","DOIUrl":null,"url":null,"abstract":"A Time‐Temperature‐Transformation (TTT) diagram is created for the curing reaction of a DGEBA‐based epoxy resin. It results from a kinetic analysis performed by means of dynamical DSC measurements; a gelation curve determined with isothermal and dynamical rheological tests; and a vitrification curve obtained from temperature‐modulated dynamic DSC measurements. The resulting diagram is validated by comparison of isothermal measurements with the corresponding calculated curves.This article is protected by copyright. All rights reserved","PeriodicalId":18157,"journal":{"name":"Macromolecular Theory and Simulations","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Time‐Temperature‐Transformation (TTT) Cure Diagram of an Epoxy‐Amine System\",\"authors\":\"Claire Strasser, Elena Moukhina, Jürgen Hartmann\",\"doi\":\"10.1002/mats.202400039\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A Time‐Temperature‐Transformation (TTT) diagram is created for the curing reaction of a DGEBA‐based epoxy resin. It results from a kinetic analysis performed by means of dynamical DSC measurements; a gelation curve determined with isothermal and dynamical rheological tests; and a vitrification curve obtained from temperature‐modulated dynamic DSC measurements. The resulting diagram is validated by comparison of isothermal measurements with the corresponding calculated curves.This article is protected by copyright. All rights reserved\",\"PeriodicalId\":18157,\"journal\":{\"name\":\"Macromolecular Theory and Simulations\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-06-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Theory and Simulations\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/mats.202400039\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Theory and Simulations","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/mats.202400039","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Time‐Temperature‐Transformation (TTT) Cure Diagram of an Epoxy‐Amine System
A Time‐Temperature‐Transformation (TTT) diagram is created for the curing reaction of a DGEBA‐based epoxy resin. It results from a kinetic analysis performed by means of dynamical DSC measurements; a gelation curve determined with isothermal and dynamical rheological tests; and a vitrification curve obtained from temperature‐modulated dynamic DSC measurements. The resulting diagram is validated by comparison of isothermal measurements with the corresponding calculated curves.This article is protected by copyright. All rights reserved
期刊介绍:
Macromolecular Theory and Simulations is the only high-quality polymer science journal dedicated exclusively to theory and simulations, covering all aspects from macromolecular theory to advanced computer simulation techniques.