Mitrabhanu Behera , Rajashree Panda , R. Arun Kumar , R.K. Padhi , Kaushal Kumar
{"title":"利用新型掺镝硼酸钇钙(Dy: Y2CaB10O19)荧光粉制造高能效 Pi-G 结构:有利于绿色技术的高效冷白光材料","authors":"Mitrabhanu Behera , Rajashree Panda , R. Arun Kumar , R.K. Padhi , Kaushal Kumar","doi":"10.1016/j.dyepig.2024.112255","DOIUrl":null,"url":null,"abstract":"<div><p>Novel polycrystalline phosphor-yttrium calcium borate doped with dysprosium ions (Dy<sup>3+</sup>: Y<sub>2</sub>CaB<sub>10</sub>O<sub>19</sub>) was synthesized for the first time by solid-state reaction technique. The crystal structure was found to be monoclinic having C2 space group. SEM was performed to analyze the surface morphology of the phosphor materials and to assess the distribution of phosphor particles in the glass matrix. Fourier transform infrared (FTIR) spectroscopy of the samples was studied to know the molecules present. The emission spectra by 350 nm excitation possessed characteristic peaks at 480 nm (blue) and 577 nm (yellow). The CIE chromaticity co-ordinate and correlated color temperature (CCT) were deduced to be (x = 0.3384, y = 0.3823) and 5297 K respectively. Luminescence decay time for the optimized phosphor was determined to be 0.70 ms. The prepared phosphors were embedded in the glass matrix at an elevated temperature of 1000 °C. The transmittance spectra of the prepared glass materials were recorded to analyze its transparency in the visible region. The internal quantum yield was deduced to be 53.91 %.</p></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":null,"pages":null},"PeriodicalIF":4.1000,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication of energy efficient P-i-G structure with novel dysprosium-doped yttrium calcium borate (Dy: Y2CaB10O19) phosphors: Highly efficient materials for cool white light emission conducive to green technology\",\"authors\":\"Mitrabhanu Behera , Rajashree Panda , R. Arun Kumar , R.K. Padhi , Kaushal Kumar\",\"doi\":\"10.1016/j.dyepig.2024.112255\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Novel polycrystalline phosphor-yttrium calcium borate doped with dysprosium ions (Dy<sup>3+</sup>: Y<sub>2</sub>CaB<sub>10</sub>O<sub>19</sub>) was synthesized for the first time by solid-state reaction technique. The crystal structure was found to be monoclinic having C2 space group. SEM was performed to analyze the surface morphology of the phosphor materials and to assess the distribution of phosphor particles in the glass matrix. Fourier transform infrared (FTIR) spectroscopy of the samples was studied to know the molecules present. The emission spectra by 350 nm excitation possessed characteristic peaks at 480 nm (blue) and 577 nm (yellow). The CIE chromaticity co-ordinate and correlated color temperature (CCT) were deduced to be (x = 0.3384, y = 0.3823) and 5297 K respectively. Luminescence decay time for the optimized phosphor was determined to be 0.70 ms. The prepared phosphors were embedded in the glass matrix at an elevated temperature of 1000 °C. The transmittance spectra of the prepared glass materials were recorded to analyze its transparency in the visible region. The internal quantum yield was deduced to be 53.91 %.</p></div>\",\"PeriodicalId\":302,\"journal\":{\"name\":\"Dyes and Pigments\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2024-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Dyes and Pigments\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0143720824003206\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dyes and Pigments","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0143720824003206","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Fabrication of energy efficient P-i-G structure with novel dysprosium-doped yttrium calcium borate (Dy: Y2CaB10O19) phosphors: Highly efficient materials for cool white light emission conducive to green technology
Novel polycrystalline phosphor-yttrium calcium borate doped with dysprosium ions (Dy3+: Y2CaB10O19) was synthesized for the first time by solid-state reaction technique. The crystal structure was found to be monoclinic having C2 space group. SEM was performed to analyze the surface morphology of the phosphor materials and to assess the distribution of phosphor particles in the glass matrix. Fourier transform infrared (FTIR) spectroscopy of the samples was studied to know the molecules present. The emission spectra by 350 nm excitation possessed characteristic peaks at 480 nm (blue) and 577 nm (yellow). The CIE chromaticity co-ordinate and correlated color temperature (CCT) were deduced to be (x = 0.3384, y = 0.3823) and 5297 K respectively. Luminescence decay time for the optimized phosphor was determined to be 0.70 ms. The prepared phosphors were embedded in the glass matrix at an elevated temperature of 1000 °C. The transmittance spectra of the prepared glass materials were recorded to analyze its transparency in the visible region. The internal quantum yield was deduced to be 53.91 %.
期刊介绍:
Dyes and Pigments covers the scientific and technical aspects of the chemistry and physics of dyes, pigments and their intermediates. Emphasis is placed on the properties of the colouring matters themselves rather than on their applications or the system in which they may be applied.
Thus the journal accepts research and review papers on the synthesis of dyes, pigments and intermediates, their physical or chemical properties, e.g. spectroscopic, surface, solution or solid state characteristics, the physical aspects of their preparation, e.g. precipitation, nucleation and growth, crystal formation, liquid crystalline characteristics, their photochemical, ecological or biological properties and the relationship between colour and chemical constitution. However, papers are considered which deal with the more fundamental aspects of colourant application and of the interactions of colourants with substrates or media.
The journal will interest a wide variety of workers in a range of disciplines whose work involves dyes, pigments and their intermediates, and provides a platform for investigators with common interests but diverse fields of activity such as cosmetics, reprographics, dye and pigment synthesis, medical research, polymers, etc.