在热和微波条件下合成 1-金刚烷基-4-烷基-1H-1,2,3-三唑

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-05-01 DOI:10.1016/j.mencom.2024.04.030

Rishat I. Aminov

引用次数: 0

摘要

研究发现，铝酸离子液体 [Et3NH]+[Al2Cl7]- 是卤代金刚烷与三甲基硅叠氮化物反应生成相应叠氮金刚烷的有效催化剂，产率为 92-98%。利用 "点击化学"，在热或微波条件下，将由此获得的叠氮金刚烷与末端炔烃反应，可干净利落地得到预期的 1,4 二甲基二取代 1,2,3 三唑，其中一些是新的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of 1-adamantyl-4-alkyl-1H-1,2,3-triazoles under thermal and microwave conditions

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Synthesis of 1-adamantyl-4-alkyl-1H-1,2,3-triazoles under thermal and microwave conditions

Aluminate ionic liquid [Et₃NH]⁺[Al₂Cl₇]⁻ was found to be an effective catalyst for the reactions of haloadamantanes with trimethylsilyl azide to produce the corresponding azido- adamantanes in 92–98% yields. Using ‘click chemistry’, the thus obtained azidoadamantanes were reacted with terminal alkynes under thermal or microwave conditions to cleanly afford the expected 1,4-disubstituted 1,2,3-triazoles some of which were new.

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.