{"title":"有效分离并全面量化大豆油中的 EPA16 多环芳烃、EU15+1 多环芳烃、17 种卤代多环芳烃和 18 种含氧多环芳烃","authors":"Xin Ma, Jingya Wang, Shimin Wu","doi":"10.1016/j.foodcont.2024.110605","DOIUrl":null,"url":null,"abstract":"<div><p>Halogenated and oxygenated polycyclic aromatic hydrocarbons (XPAHs and OPAHs) have attracted increasing attention due to their considerable or higher toxicity than the corresponding parent PAHs. However, only a few kinds of PAH derivatives were monitored in vegetable oils due to the difficulties in analysis. This study aimed to establish analytical methods for 24 PAHs, 17 XPAHs and 18 OPAHs in soybean oil. The modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) pretreatment followed by GC-MS/MS or UPLC-MS/MS analysis was applied in this study. The results showed that the modified QuEChERS pretreatment could successfully extract 56 PAHs and derivatives in soybean oil, which saved organic solvent to a great extent. Simultaneous determination of EPA16 PAHs, EU15 + 1 PAHs, 17 XPAHs, and 12 OPAHs in soybean oil was achieved by GC-MS/MS analysis, which had recoveries of 61.33–111.61% and relative standard deviations (RSDs) of 1.35–19.89%. UPLC-MS/MS analysis obtained recoveries from 51.61% to 109.45% and RSDs from 1.31% to 15.05% for 14 OPAHs. As a supplement to GC-MS/MS, UPLC-MS/MS exhibited high sensitivity to <em>ortho</em>-OPAHs and benzo[a]pyrene–quinone isomers. Through GC-MS/MS and UPLC-MS/MS analyses, the concentrations of two XPAHs and ten OPAHs in soybean oils were firstly reported. In short, this study offered guidance for comprehensive analyses of PAHs, XPAHs, and OPAHs in vegetable oils.</p></div>","PeriodicalId":319,"journal":{"name":"Food Control","volume":null,"pages":null},"PeriodicalIF":5.6000,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effective isolation and comprehensive quantification of EPA16 PAHs, EU15+1 PAHs, 17 halogenated PAHs, and 18 oxygenated PAHs in soybean oil\",\"authors\":\"Xin Ma, Jingya Wang, Shimin Wu\",\"doi\":\"10.1016/j.foodcont.2024.110605\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Halogenated and oxygenated polycyclic aromatic hydrocarbons (XPAHs and OPAHs) have attracted increasing attention due to their considerable or higher toxicity than the corresponding parent PAHs. However, only a few kinds of PAH derivatives were monitored in vegetable oils due to the difficulties in analysis. This study aimed to establish analytical methods for 24 PAHs, 17 XPAHs and 18 OPAHs in soybean oil. The modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) pretreatment followed by GC-MS/MS or UPLC-MS/MS analysis was applied in this study. The results showed that the modified QuEChERS pretreatment could successfully extract 56 PAHs and derivatives in soybean oil, which saved organic solvent to a great extent. Simultaneous determination of EPA16 PAHs, EU15 + 1 PAHs, 17 XPAHs, and 12 OPAHs in soybean oil was achieved by GC-MS/MS analysis, which had recoveries of 61.33–111.61% and relative standard deviations (RSDs) of 1.35–19.89%. UPLC-MS/MS analysis obtained recoveries from 51.61% to 109.45% and RSDs from 1.31% to 15.05% for 14 OPAHs. As a supplement to GC-MS/MS, UPLC-MS/MS exhibited high sensitivity to <em>ortho</em>-OPAHs and benzo[a]pyrene–quinone isomers. Through GC-MS/MS and UPLC-MS/MS analyses, the concentrations of two XPAHs and ten OPAHs in soybean oils were firstly reported. In short, this study offered guidance for comprehensive analyses of PAHs, XPAHs, and OPAHs in vegetable oils.</p></div>\",\"PeriodicalId\":319,\"journal\":{\"name\":\"Food Control\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-05-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Food Control\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0956713524003220\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"FOOD SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Food Control","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0956713524003220","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"FOOD SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Effective isolation and comprehensive quantification of EPA16 PAHs, EU15+1 PAHs, 17 halogenated PAHs, and 18 oxygenated PAHs in soybean oil
Halogenated and oxygenated polycyclic aromatic hydrocarbons (XPAHs and OPAHs) have attracted increasing attention due to their considerable or higher toxicity than the corresponding parent PAHs. However, only a few kinds of PAH derivatives were monitored in vegetable oils due to the difficulties in analysis. This study aimed to establish analytical methods for 24 PAHs, 17 XPAHs and 18 OPAHs in soybean oil. The modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) pretreatment followed by GC-MS/MS or UPLC-MS/MS analysis was applied in this study. The results showed that the modified QuEChERS pretreatment could successfully extract 56 PAHs and derivatives in soybean oil, which saved organic solvent to a great extent. Simultaneous determination of EPA16 PAHs, EU15 + 1 PAHs, 17 XPAHs, and 12 OPAHs in soybean oil was achieved by GC-MS/MS analysis, which had recoveries of 61.33–111.61% and relative standard deviations (RSDs) of 1.35–19.89%. UPLC-MS/MS analysis obtained recoveries from 51.61% to 109.45% and RSDs from 1.31% to 15.05% for 14 OPAHs. As a supplement to GC-MS/MS, UPLC-MS/MS exhibited high sensitivity to ortho-OPAHs and benzo[a]pyrene–quinone isomers. Through GC-MS/MS and UPLC-MS/MS analyses, the concentrations of two XPAHs and ten OPAHs in soybean oils were firstly reported. In short, this study offered guidance for comprehensive analyses of PAHs, XPAHs, and OPAHs in vegetable oils.
期刊介绍:
Food Control is an international journal that provides essential information for those involved in food safety and process control.
Food Control covers the below areas that relate to food process control or to food safety of human foods:
• Microbial food safety and antimicrobial systems
• Mycotoxins
• Hazard analysis, HACCP and food safety objectives
• Risk assessment, including microbial and chemical hazards
• Quality assurance
• Good manufacturing practices
• Food process systems design and control
• Food Packaging technology and materials in contact with foods
• Rapid methods of analysis and detection, including sensor technology
• Codes of practice, legislation and international harmonization
• Consumer issues
• Education, training and research needs.
The scope of Food Control is comprehensive and includes original research papers, authoritative reviews, short communications, comment articles that report on new developments in food control, and position papers.