{"title":"用于催化铃木-宫浦偶联反应的钴支撑[Aemim]Br 离子液体","authors":"Karthikeyan Parasuraman , Uthayanila Selvarasu , Venkatesan Kasi , Ramasamy Shanmugapriya","doi":"10.1016/j.cinorg.2024.100056","DOIUrl":null,"url":null,"abstract":"<div><p>This communication describes a highly recyclable, ecologically friendly, ionic liquid catalyst supported by cobalt that is active in the Suzuki-Miyaura reaction at 70 °C. To be more precise, the procedure is initiated with a special form of the ecologically safe solvent 3-(2-aminoethyl)-1-methyl-1H-imidazole-3-ium bromide [Aemim]Br. A few benefits of the coupling process include its simplicity of use, broad range of substrate compatibility with high yields, environmental friendliness, high reaction rate, low catalyst loading (0.001 mol%), and recyclability (up to 7 cycles).</p></div>","PeriodicalId":100233,"journal":{"name":"Chemistry of Inorganic Materials","volume":"3 ","pages":"Article 100056"},"PeriodicalIF":0.0000,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949746924000247/pdfft?md5=1e78e2a9f89ce8a11ecb1a16ea2de0a9&pid=1-s2.0-S2949746924000247-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Cobalt -supported [Aemim]Br ionic liquid for the catalytic suzuki-miyaura coupling reactions\",\"authors\":\"Karthikeyan Parasuraman , Uthayanila Selvarasu , Venkatesan Kasi , Ramasamy Shanmugapriya\",\"doi\":\"10.1016/j.cinorg.2024.100056\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This communication describes a highly recyclable, ecologically friendly, ionic liquid catalyst supported by cobalt that is active in the Suzuki-Miyaura reaction at 70 °C. To be more precise, the procedure is initiated with a special form of the ecologically safe solvent 3-(2-aminoethyl)-1-methyl-1H-imidazole-3-ium bromide [Aemim]Br. A few benefits of the coupling process include its simplicity of use, broad range of substrate compatibility with high yields, environmental friendliness, high reaction rate, low catalyst loading (0.001 mol%), and recyclability (up to 7 cycles).</p></div>\",\"PeriodicalId\":100233,\"journal\":{\"name\":\"Chemistry of Inorganic Materials\",\"volume\":\"3 \",\"pages\":\"Article 100056\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2949746924000247/pdfft?md5=1e78e2a9f89ce8a11ecb1a16ea2de0a9&pid=1-s2.0-S2949746924000247-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry of Inorganic Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2949746924000247\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Inorganic Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2949746924000247","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Cobalt -supported [Aemim]Br ionic liquid for the catalytic suzuki-miyaura coupling reactions
This communication describes a highly recyclable, ecologically friendly, ionic liquid catalyst supported by cobalt that is active in the Suzuki-Miyaura reaction at 70 °C. To be more precise, the procedure is initiated with a special form of the ecologically safe solvent 3-(2-aminoethyl)-1-methyl-1H-imidazole-3-ium bromide [Aemim]Br. A few benefits of the coupling process include its simplicity of use, broad range of substrate compatibility with high yields, environmental friendliness, high reaction rate, low catalyst loading (0.001 mol%), and recyclability (up to 7 cycles).
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