A. Z. Yumaguen, E. S. Babitova, M. V. Logunov, M. D. Karavan, P. V. Kozlov, A. V. Konnikov, I. V. Smirnov
{"title":"用对-壬基钙[6]烯萃取剂从马雅克模型碱性 HLW 中回收铯-137 的动态测试","authors":"A. Z. Yumaguen, E. S. Babitova, M. V. Logunov, M. D. Karavan, P. V. Kozlov, A. V. Konnikov, I. V. Smirnov","doi":"10.1134/S106636222402005X","DOIUrl":null,"url":null,"abstract":"<p>The article presents the results of studies on composition optimization, properties, and laboratory dynamic tests of extraction mixtures based on <i>p</i>-isononylcalix[6]arene for the alkaline HLW purification to remove <sup>137</sup>Cs. The distribution of <sup>137</sup>Cs among the products of the technological scheme is presented and the raffinate purification factor to remove <sup>137</sup>Cs are determined. It was revealed that, in the case of using nitric acid as a stripping solution, nitrosation of <i>p</i>-isononylcalix[6]arene is possible in the technological process. The composition of the resulting product was determined. To prevent nitrosation of <i>p</i>-isononylcalix[6]arene, formic acid was used in the stripping stage, which ensured stable operation of the extraction setup for 48 h while <sup>137</sup>Cs extraction from model alkaline HLW was at a level of 99.7%.</p>","PeriodicalId":747,"journal":{"name":"Radiochemistry","volume":"66 2","pages":"163 - 177"},"PeriodicalIF":0.9000,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dynamic Tests of Cesium-137 Recovery from the Mayak Model Alkaline HLW with p-Isononylcalix[6]arene-based Extractant\",\"authors\":\"A. Z. Yumaguen, E. S. Babitova, M. V. Logunov, M. D. Karavan, P. V. Kozlov, A. V. Konnikov, I. V. Smirnov\",\"doi\":\"10.1134/S106636222402005X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The article presents the results of studies on composition optimization, properties, and laboratory dynamic tests of extraction mixtures based on <i>p</i>-isononylcalix[6]arene for the alkaline HLW purification to remove <sup>137</sup>Cs. The distribution of <sup>137</sup>Cs among the products of the technological scheme is presented and the raffinate purification factor to remove <sup>137</sup>Cs are determined. It was revealed that, in the case of using nitric acid as a stripping solution, nitrosation of <i>p</i>-isononylcalix[6]arene is possible in the technological process. The composition of the resulting product was determined. To prevent nitrosation of <i>p</i>-isononylcalix[6]arene, formic acid was used in the stripping stage, which ensured stable operation of the extraction setup for 48 h while <sup>137</sup>Cs extraction from model alkaline HLW was at a level of 99.7%.</p>\",\"PeriodicalId\":747,\"journal\":{\"name\":\"Radiochemistry\",\"volume\":\"66 2\",\"pages\":\"163 - 177\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-05-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S106636222402005X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiochemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S106636222402005X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Dynamic Tests of Cesium-137 Recovery from the Mayak Model Alkaline HLW with p-Isononylcalix[6]arene-based Extractant
The article presents the results of studies on composition optimization, properties, and laboratory dynamic tests of extraction mixtures based on p-isononylcalix[6]arene for the alkaline HLW purification to remove 137Cs. The distribution of 137Cs among the products of the technological scheme is presented and the raffinate purification factor to remove 137Cs are determined. It was revealed that, in the case of using nitric acid as a stripping solution, nitrosation of p-isononylcalix[6]arene is possible in the technological process. The composition of the resulting product was determined. To prevent nitrosation of p-isononylcalix[6]arene, formic acid was used in the stripping stage, which ensured stable operation of the extraction setup for 48 h while 137Cs extraction from model alkaline HLW was at a level of 99.7%.
期刊介绍：
Radiochemistry is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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