测定棕榈油燃料灰(POFA)在麻风树油酯交换反应生产生物柴油过程中的异相催化性能

A.R. Uba, H. U. Jamo, U. I. Ismail, F.U. Musa, S.H. Gwadabe
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引用次数: 0

摘要

使用化石燃料生产能源的高能源需求和对环境的负面影响,引发了人们对可持续经济增长过度依赖化石燃料的质疑。生物柴油是解决上述问题的可再生替代方案之一。通过麻风树油的酯交换反应,研究了棕榈油燃料灰(POFA)在生产生物柴油过程中的异相催化性能。分别使用扫描电子显微镜(SEM)和 X 射线荧光光谱(XRF)对 POFA 的形态和化学特性进行了研究。对粗麻风树油进行酯交换反应,并使用 0.1wt%、0.2wt%、0.3wt%、0.4wt% 和 0.5wt% 的 POFA 作为异相催化剂。傅立叶变换红外(FTIR)被用来确定样品的官能团。扫描电子显微镜显示 POFA 存在多孔结构、纹理和不规则形状,而 XRF 则显示 POFA 主要由 SiO2(79.45%)组成。当使用 0.2wt% 的 POFA 时,生物柴油产量的最大百分比为 92.30%。这表明 POFA 可用作生产生物柴油的异相催化剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The determination of heterogeneous catalytic performance of Palm Oil Fuel Ash (POFA) in the production of biodiesel via transesterification of Jatropha oil
The high energy demand with the negative environmental impacts of using fossil fuel for energy generations raised question on over dependability on it for sustainable economic growth. Biodiesel tend to be one of the renewable alternative solutions towards the above problems. Biodiesel can be produced through various methods such as transesterification, micro emulsion and pyrolysis The heterogeneous catalytic performance of Palm Oil Fuel Ash (POFA) in the production of biodiesel via transesterification of jatropha oil was investigated. The morphological and chemical properties of POFA were studied using Scanning Electron Microscopy (SEM) and X-ray Fluoroscopy (XRF) respectively. The crude Jatropha oil was transesterified and 0.1 wt%, 0.2 wt%, 0.3wt%, 0.4wt% and 0.5wt% of POFA were used as heterogeneous catalyst. Fourier Transform Infrared (FTIR) has been used to determine the functional group of the samples. SEM indicates the presence porous structure, texture and irregular shape on POFA while XRF shows that it comprises mainly of SiO2 (79.45 %). The maximum percentage of biodiesel yield was 92.30% at the application of 0.2wt% POFA. This shows that POFA can be used as a heterogeneous catalyst in the production of biodiesel.
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