{"title":"改性玉米淀粉/GO 复合气凝胶对重金属离子铬 (III) 的高效吸附","authors":"Dequan Wei, Shenghua Lv, Shanshan Zhang, Jingjing Zuo, Shan Liang, Juhui Yang, Jialin Wang","doi":"10.1007/s13726-024-01326-5","DOIUrl":null,"url":null,"abstract":"<div><p>Starch is a natural polymer containing a large number of active hydroxyl groups, which make it an ideal material for preparation of adsorption functional aerogels. In this work, a modified carboxymethyl corn starch/organic glass composite aerogel (CMSHA-GO) was successfully prepared using starch as raw material and hexamethylenediamine as cross-linking agent. It showed significant adsorption properties for heavy metal ions. When the composite aerogel was introduced with 10 mg GO, the adsorption capacity of CMSHA-GO<sub>10</sub> aerogel for heavy metal ions was in the order of Cr<sup>3+</sup> > Ni<sup>2+</sup> > Cu<sup>2+</sup> > Cr(VI) > Pb<sup>2+</sup>, while its adsorption performance for heavy metal ion Cr<sup>3+</sup> was mainly discussed. The structures and morphologies of the composite aerogels were characterized by FTIR, XRD, and SEM techniques. The results showed that the CMSHA-GO composite aerogel has a stable three-dimensional mesh-like porous structure with good conditions for metal ion adsorption. In addition, the effects of different GO contents, pH values, and time conditions on the adsorption of metal ions by the CMSHA-GO composite aerogel were discussed. When the weight ratio of carboxymethyl starch: hexanediamine: GO was 10:0.1:0.1, the CMSHA-GO<sub>10</sub> composite aerogel showed the best adsorption performance for Cr<sup>3+</sup> ions. The adsorption equilibrium was reached within 3 h at an initial Cr<sup>3+</sup> concentration of 500 mg·L<sup>−1</sup>, with a maximum equilibrium adsorption capacity (<i>q</i><sub>e</sub><sup>cale</sup>) of 212.7 mg/g.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":"33 10","pages":"1469 - 1480"},"PeriodicalIF":2.4000,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Efficient adsorption of heavy metal ions chromium (III) by modified corn starch/GO composite aerogel\",\"authors\":\"Dequan Wei, Shenghua Lv, Shanshan Zhang, Jingjing Zuo, Shan Liang, Juhui Yang, Jialin Wang\",\"doi\":\"10.1007/s13726-024-01326-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Starch is a natural polymer containing a large number of active hydroxyl groups, which make it an ideal material for preparation of adsorption functional aerogels. In this work, a modified carboxymethyl corn starch/organic glass composite aerogel (CMSHA-GO) was successfully prepared using starch as raw material and hexamethylenediamine as cross-linking agent. It showed significant adsorption properties for heavy metal ions. When the composite aerogel was introduced with 10 mg GO, the adsorption capacity of CMSHA-GO<sub>10</sub> aerogel for heavy metal ions was in the order of Cr<sup>3+</sup> > Ni<sup>2+</sup> > Cu<sup>2+</sup> > Cr(VI) > Pb<sup>2+</sup>, while its adsorption performance for heavy metal ion Cr<sup>3+</sup> was mainly discussed. The structures and morphologies of the composite aerogels were characterized by FTIR, XRD, and SEM techniques. The results showed that the CMSHA-GO composite aerogel has a stable three-dimensional mesh-like porous structure with good conditions for metal ion adsorption. In addition, the effects of different GO contents, pH values, and time conditions on the adsorption of metal ions by the CMSHA-GO composite aerogel were discussed. When the weight ratio of carboxymethyl starch: hexanediamine: GO was 10:0.1:0.1, the CMSHA-GO<sub>10</sub> composite aerogel showed the best adsorption performance for Cr<sup>3+</sup> ions. The adsorption equilibrium was reached within 3 h at an initial Cr<sup>3+</sup> concentration of 500 mg·L<sup>−1</sup>, with a maximum equilibrium adsorption capacity (<i>q</i><sub>e</sub><sup>cale</sup>) of 212.7 mg/g.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":601,\"journal\":{\"name\":\"Iranian Polymer Journal\",\"volume\":\"33 10\",\"pages\":\"1469 - 1480\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2024-05-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Iranian Polymer Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13726-024-01326-5\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Iranian Polymer Journal","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s13726-024-01326-5","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Efficient adsorption of heavy metal ions chromium (III) by modified corn starch/GO composite aerogel
Starch is a natural polymer containing a large number of active hydroxyl groups, which make it an ideal material for preparation of adsorption functional aerogels. In this work, a modified carboxymethyl corn starch/organic glass composite aerogel (CMSHA-GO) was successfully prepared using starch as raw material and hexamethylenediamine as cross-linking agent. It showed significant adsorption properties for heavy metal ions. When the composite aerogel was introduced with 10 mg GO, the adsorption capacity of CMSHA-GO10 aerogel for heavy metal ions was in the order of Cr3+ > Ni2+ > Cu2+ > Cr(VI) > Pb2+, while its adsorption performance for heavy metal ion Cr3+ was mainly discussed. The structures and morphologies of the composite aerogels were characterized by FTIR, XRD, and SEM techniques. The results showed that the CMSHA-GO composite aerogel has a stable three-dimensional mesh-like porous structure with good conditions for metal ion adsorption. In addition, the effects of different GO contents, pH values, and time conditions on the adsorption of metal ions by the CMSHA-GO composite aerogel were discussed. When the weight ratio of carboxymethyl starch: hexanediamine: GO was 10:0.1:0.1, the CMSHA-GO10 composite aerogel showed the best adsorption performance for Cr3+ ions. The adsorption equilibrium was reached within 3 h at an initial Cr3+ concentration of 500 mg·L−1, with a maximum equilibrium adsorption capacity (qecale) of 212.7 mg/g.
期刊介绍：
Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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