具有二硫桥配体的三(吡唑基)硼酸铼(V)硫酸盐配合物:合成与结构

IF 1.1 3区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR
I. V. Skabitskii, S. S. Shapovalov
{"title":"具有二硫桥配体的三(吡唑基)硼酸铼(V)硫酸盐配合物:合成与结构","authors":"I. V. Skabitskii,&nbsp;S. S. Shapovalov","doi":"10.1134/S1070328423601152","DOIUrl":null,"url":null,"abstract":"<p>The reaction of TpReOCl(S<sup><i>t</i></sup>Bu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(µ-S<sup><i>t</i></sup>Bu)]<sub>2</sub>(µ-S<sub>2</sub>) (<b>I</b>). Complex <b>I</b> can also be synthesized by the reaction of TpReO(S<sup><i>t</i></sup>Bu)<sub>2</sub> with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]<sub>2</sub>(µ-S<sub>2</sub>)(µ-S) (<b>II</b>) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex <b>I</b> with dichloromethane containing the molecules with different conformations of the Re<sub>2</sub>S<sub>2</sub> fragment (<b>Ia</b> and <b>Ib</b>) and complex <b>II</b> are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for <b>Ia</b>, <b>Ib</b>, and <b>II</b>, respectively).</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 2","pages":"156 - 162"},"PeriodicalIF":1.1000,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure\",\"authors\":\"I. V. Skabitskii,&nbsp;S. S. Shapovalov\",\"doi\":\"10.1134/S1070328423601152\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reaction of TpReOCl(S<sup><i>t</i></sup>Bu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(µ-S<sup><i>t</i></sup>Bu)]<sub>2</sub>(µ-S<sub>2</sub>) (<b>I</b>). Complex <b>I</b> can also be synthesized by the reaction of TpReO(S<sup><i>t</i></sup>Bu)<sub>2</sub> with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]<sub>2</sub>(µ-S<sub>2</sub>)(µ-S) (<b>II</b>) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex <b>I</b> with dichloromethane containing the molecules with different conformations of the Re<sub>2</sub>S<sub>2</sub> fragment (<b>Ia</b> and <b>Ib</b>) and complex <b>II</b> are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for <b>Ia</b>, <b>Ib</b>, and <b>II</b>, respectively).</p>\",\"PeriodicalId\":759,\"journal\":{\"name\":\"Russian Journal of Coordination Chemistry\",\"volume\":\"50 2\",\"pages\":\"156 - 162\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Coordination Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070328423601152\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423601152","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

摘要

摘要TpReOCl(StBu)(Tp = 三(吡唑基)硼酸阴离子)与二硫化钠在二甲氧基乙烷中反应生成了新的双核铼络合物 [TpReO(µ-StBu)]2(µ-S2)(I)。络合物 I 还可以通过 TpReO(StBu)2 与溴化锰(II)悬浮液在甲苯中的反应合成,同时对其中一个配体进行脱烷基化,形成另一个含有桥接硫化物和二硫化物配体的新络合物 [TpReO]2(µ-S2)(µ-S)(II)。通过 X 射线衍射 (XRD)(CIF 文件ССDC 编号 2262677、2262678 和 2267423,分别代表 Ia、Ib 和 II)研究了络合物 I 与二氯甲烷的两种结晶溶液的结构,其中络合物 I 含有不同构象的 Re2S2 片段分子(Ia 和 Ib),络合物 II 含有不同构象的 Re2S2 片段分子(Ia 和 Ib)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure

Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure

Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure

The reaction of TpReOCl(StBu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(µ-StBu)]2(µ-S2) (I). Complex I can also be synthesized by the reaction of TpReO(StBu)2 with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]2(µ-S2)(µ-S) (II) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex I with dichloromethane containing the molecules with different conformations of the Re2S2 fragment (Ia and Ib) and complex II are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for Ia, Ib, and II, respectively).

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Russian Journal of Coordination Chemistry
Russian Journal of Coordination Chemistry 化学-无机化学与核化学
CiteScore
2.40
自引率
15.80%
发文量
85
审稿时长
7.2 months
期刊介绍: Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信