{"title":"具有二硫桥配体的三(吡唑基)硼酸铼(V)硫酸盐配合物：合成与结构","authors":"I. V. Skabitskii, S. S. Shapovalov","doi":"10.1134/S1070328423601152","DOIUrl":null,"url":null,"abstract":"<p>The reaction of TpReOCl(S<sup><i>t</i></sup>Bu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(µ-S<sup><i>t</i></sup>Bu)]<sub>2</sub>(µ-S<sub>2</sub>) (<b>I</b>). Complex <b>I</b> can also be synthesized by the reaction of TpReO(S<sup><i>t</i></sup>Bu)<sub>2</sub> with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]<sub>2</sub>(µ-S<sub>2</sub>)(µ-S) (<b>II</b>) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex <b>I</b> with dichloromethane containing the molecules with different conformations of the Re<sub>2</sub>S<sub>2</sub> fragment (<b>Ia</b> and <b>Ib</b>) and complex <b>II</b> are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for <b>Ia</b>, <b>Ib</b>, and <b>II</b>, respectively).</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure\",\"authors\":\"I. V. Skabitskii, S. S. Shapovalov\",\"doi\":\"10.1134/S1070328423601152\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reaction of TpReOCl(S<sup><i>t</i></sup>Bu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(µ-S<sup><i>t</i></sup>Bu)]<sub>2</sub>(µ-S<sub>2</sub>) (<b>I</b>). Complex <b>I</b> can also be synthesized by the reaction of TpReO(S<sup><i>t</i></sup>Bu)<sub>2</sub> with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]<sub>2</sub>(µ-S<sub>2</sub>)(µ-S) (<b>II</b>) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex <b>I</b> with dichloromethane containing the molecules with different conformations of the Re<sub>2</sub>S<sub>2</sub> fragment (<b>Ia</b> and <b>Ib</b>) and complex <b>II</b> are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for <b>Ia</b>, <b>Ib</b>, and <b>II</b>, respectively).</p>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070328423601152\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423601152","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
摘要TpReOCl(StBu)（Tp = 三(吡唑基)硼酸阴离子）与二硫化钠在二甲氧基乙烷中反应生成了新的双核铼络合物 [TpReO(µ-StBu)]2(µ-S2)(I)。络合物 I 还可以通过 TpReO(StBu)2 与溴化锰（II）悬浮液在甲苯中的反应合成，同时对其中一个配体进行脱烷基化，形成另一个含有桥接硫化物和二硫化物配体的新络合物 [TpReO]2(µ-S2)(µ-S)（II）。通过 X 射线衍射 (XRD)（CIF 文件ССDC 编号 2262677、2262678 和 2267423，分别代表 Ia、Ib 和 II）研究了络合物 I 与二氯甲烷的两种结晶溶液的结构，其中络合物 I 含有不同构象的 Re2S2 片段分子（Ia 和 Ib），络合物 II 含有不同构象的 Re2S2 片段分子（Ia 和 Ib）。
Rhenium(V) Tris(pyrazolyl)borate Thiolate Complex with the Disulfide Bridging Ligand: Synthesis and Structure
The reaction of TpReOCl(StBu) (Tp = tris(pyrazolyl)borate anion) with sodium disulfide in dimethoxyethane affords the new binuclear rhenium complex [TpReO(µ-StBu)]2(µ-S2) (I). Complex I can also be synthesized by the reaction of TpReO(StBu)2 with a suspension of manganese(II) bromide in toluene accompanied by the dealkylation of one of the ligands to form one more new complex [TpReO]2(µ-S2)(µ-S) (II) containing the bridging sulfide and disulfide ligands. The structures of two crystalline solvates of complex I with dichloromethane containing the molecules with different conformations of the Re2S2 fragment (Ia and Ib) and complex II are studied by X-ray diffraction (XRD) (CIF files ССDC nos. 2262677, 2262678, and 2267423 for Ia, Ib, and II, respectively).
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