铟(0)介导的羰基化合物机械化学巴比尔烯丙基化:疏水性试剂意外的不溶水添加效应†。

Nuri Kim, Eun Sul Go and Jeung Gon Kim
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引用次数: 0

摘要

在机械化学球磨条件下,铟介导的巴比尔烯丙基化反应在加入水后表现出积极的效果。尽管固态疏水醛具有不溶性,但少量水作为添加剂可选择性地促进它们的烯丙基化。本文还展示了这种方法的广泛适用性和可扩展性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Mechanochemical indium(0)-mediated Barbier allylation of carbonyl compounds: unexpected immiscible water additive effect for hydrophobic reagents†

Mechanochemical indium(0)-mediated Barbier allylation of carbonyl compounds: unexpected immiscible water additive effect for hydrophobic reagents†

Indium-mediated Barbier allylation exhibited a positive effect with the addition of water under mechanochemical ball-milling conditions. A small amount of water as an additive selectively boosted the allylation of solid-state hydrophobic aldehydes despite their immiscibility. The broad scope and scalability of this method are also demonstrated herein.

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