{"title":"铟(0)介导的羰基化合物机械化学巴比尔烯丙基化：疏水性试剂意外的不溶水添加效应†。","authors":"Nuri Kim, Eun Sul Go and Jeung Gon Kim","doi":"10.1039/D4MR00005F","DOIUrl":null,"url":null,"abstract":"<p >Indium-mediated Barbier allylation exhibited a positive effect with the addition of water under mechanochemical ball-milling conditions. A small amount of water as an additive selectively boosted the allylation of solid-state hydrophobic aldehydes despite their immiscibility. The broad scope and scalability of this method are also demonstrated herein.</p>","PeriodicalId":101140,"journal":{"name":"RSC Mechanochemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/mr/d4mr00005f?page=search","citationCount":"0","resultStr":"{\"title\":\"Mechanochemical indium(0)-mediated Barbier allylation of carbonyl compounds: unexpected immiscible water additive effect for hydrophobic reagents†\",\"authors\":\"Nuri Kim, Eun Sul Go and Jeung Gon Kim\",\"doi\":\"10.1039/D4MR00005F\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Indium-mediated Barbier allylation exhibited a positive effect with the addition of water under mechanochemical ball-milling conditions. A small amount of water as an additive selectively boosted the allylation of solid-state hydrophobic aldehydes despite their immiscibility. The broad scope and scalability of this method are also demonstrated herein.</p>\",\"PeriodicalId\":101140,\"journal\":{\"name\":\"RSC Mechanochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-02-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2024/mr/d4mr00005f?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"RSC Mechanochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/mr/d4mr00005f\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"RSC Mechanochemistry","FirstCategoryId":"1085","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/mr/d4mr00005f","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mechanochemical indium(0)-mediated Barbier allylation of carbonyl compounds: unexpected immiscible water additive effect for hydrophobic reagents†
Indium-mediated Barbier allylation exhibited a positive effect with the addition of water under mechanochemical ball-milling conditions. A small amount of water as an additive selectively boosted the allylation of solid-state hydrophobic aldehydes despite their immiscibility. The broad scope and scalability of this method are also demonstrated herein.
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