通过光诱导配体-金属电荷转移实现铁催化苄基 C-H 硫代化反应

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-05-28 DOI:10.1039/d4cc01574f

Kaiting Sun , Tianyi Sun , Yuxin Jiang , Jiayue Shi , Wenlu Sun , Youyou Zheng , Zhixuan Wang , Ziyu Li , Xiaoqing Lv , Xingxian Zhang , Fan Luo , Shihui Liu

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引用次数: 0

摘要

在此，我们介绍了一种通过光诱导配体到金属的电荷转移，铁催化烷基烯烃的苄基 C-H 硫代化反应。该方案操作简单，反应条件温和，使用氯化铁作为催化剂，硫醇/二硫化物作为硫源，能高效地将多种苄基 C-H 键转化为 C-S 键。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Iron-catalyzed benzylic C–H thiolation via photoinduced ligand-to-metal charge-transfer†

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Iron-catalyzed benzylic C–H thiolation via photoinduced ligand-to-metal charge-transfer†

Here, we describe an iron-catalyzed benzylic C–H thiolation of alkylarenes via photoinduced ligand-to-metal charge-transfer. The protocol features operational simplicity, mild reaction conditions, and the use of FeCl₃ as catalyst and thiols/disulfides as sulfur sources, which enables the transformation of diverse benzylic C–H bonds into C–S bonds with a high efficiency.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.