基于 1,2,4-三唑和 2-硝基-4-苯二甲酸的多孔 3D Cd(II) 配位聚合物的结构表征

IF 0.6 4区材料科学 Q4 CRYSTALLOGRAPHY

Crystallography Reports Pub Date : 2024-02-06 DOI:10.1134/s1063774522100066

C.-Y. Huang, H.-O. Zhang, H.-X. Han, Y.-B. Liu, Q. Xiao

引用次数: 0

摘要

摘要在溶热条件下合成了一种新的配位聚合物{[Cd5(三唑)6(硝基-bdc)2(DMF)4] (DMF)2(H2O)2}n (1)（三唑 = 去质子的 1,2,4-三唑，硝基-H2bdc = 2-硝基-4-苯二甲酸，DMF = N,N-二甲基甲酰胺）。配合物 1 显示出一种三维结构，其中包含由硝基-bdc2- 离子结合的二维[Cd5(三唑)6]x 网络，在这种配位聚合物中，可溶解的空隙占总晶体体积的 19.6%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Structural Characterization of a Porous 3D Cd(II) Coordination Polymer Based on 1,2,4-Triazole and 2-Nitro-4-Benzenedicarboxylic Acid

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Structural Characterization of a Porous 3D Cd(II) Coordination Polymer Based on 1,2,4-Triazole and 2-Nitro-4-Benzenedicarboxylic Acid

Abstract

A new coordination polymer {[Cd₅(triazole)₆(nitro-bdc)₂(DMF)₄] (DMF)₂(H₂O)₂}_n (1) (triazole = deprotoned 1,2,4-triazole, nitro-H₂bdc = 2-nitro-4-benzenedicarboxylic acid, DMF = N,N-dimethylformamide) was synthesized under solvothermal conditions. Complex 1 exhibited a 3D structure with 2D [Cd₅(triazole)₆]_x networks bound by nitro-bdc^2– ions, and solvent-accessible void space in the amount of 19.6% of the total crystal volume can be found in this coordination polymer.

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来源期刊

Crystallography Reports 化学-晶体学

CiteScore

1.10

自引率

28.60%

发文量

审稿时长

4-8 weeks

期刊介绍： Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.