乙醇处理的锰锌化合物去除氟化物及其吸附机理

IF 2.6 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES
Yuanyao Ye, Xueyi Yan, Xi Li, Shijing Huang, Wei Jiang, Dongqi Liu, Yongzheng Ren, Dongle Cheng
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引用次数: 0

摘要

氟是人类必需的元素,但过量摄入会对健康造成危害。吸附法被认为是应用最广泛、最经济、最方便的除氟技术之一。本研究以乙醇为溶剂,采用溶胶-凝胶法制备了锰锌乙醇(Mn-Zr-Et)复合材料,并将其用于除氟。通过批量实验研究了 Mn-Zr-Et 吸附剂对氟化物的去除性能。通过分析 Mn-Zr-Et 吸附剂的特性,进一步研究了氟的去除机理。结果表明,与 Mn-Zr 吸附剂相比,乙醇与 Mn-Zr 吸附剂的结合能大大提高氟的去除能力,在初始氟浓度为 50 mg L-1 时,Mn-Zr-Et 吸附剂的吸附量为 32.87 mg g-1。Mn-Zr-Et 吸附剂具有吸附速率快、pH 适应范围广、抗共存阴离子干扰等优点。总之,Mn-Zr-Et 复合材料是一种很有前途的高效去除氟化物的绿色吸附剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ethanol Treated Mn–Zr Compound for Fluoride Removal and its Adsorption Mechanism

Fluoride is an essential element for humans, but its excessive intake can cause harm to health. Adsorption is recommended as one of the most widely applied, affordable and convenient defluorination technologies. In the present study, Mn–Zr–Ethanol (Mn–Zr–Et) composite was prepared by sol–gel method with ethanol used as a solvent and then utilized for the fluoride removal. The removal performance of fluoride by the Mn–Zr–Et adsorbent was investigated through batch experiments. The removal mechanism of fluorine was further studied through analyzing the characteristics of the Mn–Zr–Et adsorbent. Results show that the integration of ethanol with Mn–Zr adsorbent could greatly enhance the removal capacity of fluoride when compared to the Mn–Zr adsorbent, where the adsorption capacity of Mn–Zr–Et adsorbent was 32.87 mg g−1 at the initial fluoride concentration of 50 mg L−1. The Mn–Zr–Et adsorbent had the advantages of fast adsorption rate, wide pH adaptation range and resistance to interference of coexisting anions. To sum up, the Mn–Zr–Et composite is a promising and green adsorbent for the highly efficient removal of fluoride.

Graphical Abstract

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来源期刊
CiteScore
5.40
自引率
0.00%
发文量
104
审稿时长
1.7 months
期刊介绍: International Journal of Environmental Research is a multidisciplinary journal concerned with all aspects of environment. In pursuit of these, environmentalist disciplines are invited to contribute their knowledge and experience. International Journal of Environmental Research publishes original research papers, research notes and reviews across the broad field of environment. These include but are not limited to environmental science, environmental engineering, environmental management and planning and environmental design, urban and regional landscape design and natural disaster management. Thus high quality research papers or reviews dealing with any aspect of environment are welcomed. Papers may be theoretical, interpretative or experimental.
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