Li-han ZHANG , Zuo-ying CAO , Gui-qing ZHANG , Qing-gang LI , Ming-yu WANG , Wen-juan GUAN , Sheng-xi WU , Qi DENG
{"title":"使用由 TFCA-4PC 组成的协同溶剂萃取系统从废锂离子电池酸浸出液中选择性提取镍","authors":"Li-han ZHANG , Zuo-ying CAO , Gui-qing ZHANG , Qing-gang LI , Ming-yu WANG , Wen-juan GUAN , Sheng-xi WU , Qi DENG","doi":"10.1016/S1003-6326(24)66473-3","DOIUrl":null,"url":null,"abstract":"<div><p>A synergistic solvent extraction (SSX) system consisting of tung oil-based carboxylic acid (TFCA) and isonicotinic acid ester (4PC) was proposed to selectively extract Ni over Li and Mg from acid leach solutions of spent lithium-ion batteries (LIBs). The SSX system indicates a synergistic effect of Ni which can be mainly attributed to the multiple chelate ring structure formed between TFCA and Ni, therefore resulting in strong selectivity of Ni. With optimal conditions, the extraction of Ni reaches 97.3% in a single stage, while the extractions of Mg and Li are nil and 2.29%, respectively. Further, after scrubbing with 300 mg/L NiSO<sub>4</sub>, the loaded organic solution is stripped using 0.2 mol/L H<sub>2</sub>SO<sub>4</sub>. The strip liquor containing 11.52 g/L Ni and only less than 6 mg/L Li is obtained.</p></div>","PeriodicalId":23191,"journal":{"name":"Transactions of Nonferrous Metals Society of China","volume":"34 4","pages":"Pages 1311-1320"},"PeriodicalIF":4.7000,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1003632624664733/pdf?md5=ad4fba8729adfe2947fc77cd6d0f5019&pid=1-s2.0-S1003632624664733-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Selective extraction of nickel from acid leach solution of spent lithium-ion batteries using synergistic solvent extraction system consisting of TFCA-4PC\",\"authors\":\"Li-han ZHANG , Zuo-ying CAO , Gui-qing ZHANG , Qing-gang LI , Ming-yu WANG , Wen-juan GUAN , Sheng-xi WU , Qi DENG\",\"doi\":\"10.1016/S1003-6326(24)66473-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A synergistic solvent extraction (SSX) system consisting of tung oil-based carboxylic acid (TFCA) and isonicotinic acid ester (4PC) was proposed to selectively extract Ni over Li and Mg from acid leach solutions of spent lithium-ion batteries (LIBs). The SSX system indicates a synergistic effect of Ni which can be mainly attributed to the multiple chelate ring structure formed between TFCA and Ni, therefore resulting in strong selectivity of Ni. With optimal conditions, the extraction of Ni reaches 97.3% in a single stage, while the extractions of Mg and Li are nil and 2.29%, respectively. Further, after scrubbing with 300 mg/L NiSO<sub>4</sub>, the loaded organic solution is stripped using 0.2 mol/L H<sub>2</sub>SO<sub>4</sub>. The strip liquor containing 11.52 g/L Ni and only less than 6 mg/L Li is obtained.</p></div>\",\"PeriodicalId\":23191,\"journal\":{\"name\":\"Transactions of Nonferrous Metals Society of China\",\"volume\":\"34 4\",\"pages\":\"Pages 1311-1320\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2024-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1003632624664733/pdf?md5=ad4fba8729adfe2947fc77cd6d0f5019&pid=1-s2.0-S1003632624664733-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of Nonferrous Metals Society of China\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1003632624664733\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of Nonferrous Metals Society of China","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1003632624664733","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Selective extraction of nickel from acid leach solution of spent lithium-ion batteries using synergistic solvent extraction system consisting of TFCA-4PC
A synergistic solvent extraction (SSX) system consisting of tung oil-based carboxylic acid (TFCA) and isonicotinic acid ester (4PC) was proposed to selectively extract Ni over Li and Mg from acid leach solutions of spent lithium-ion batteries (LIBs). The SSX system indicates a synergistic effect of Ni which can be mainly attributed to the multiple chelate ring structure formed between TFCA and Ni, therefore resulting in strong selectivity of Ni. With optimal conditions, the extraction of Ni reaches 97.3% in a single stage, while the extractions of Mg and Li are nil and 2.29%, respectively. Further, after scrubbing with 300 mg/L NiSO4, the loaded organic solution is stripped using 0.2 mol/L H2SO4. The strip liquor containing 11.52 g/L Ni and only less than 6 mg/L Li is obtained.
期刊介绍：
The Transactions of Nonferrous Metals Society of China (Trans. Nonferrous Met. Soc. China), founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, INSPEC, CA, METADEX, AJ and JICST.
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