复合改性沥青流变特性的宏观-微观关联分析

IF 1.3 4区 材料科学 Q3 CHEMISTRY, APPLIED
Shuang Huang, Haitao Zhang, Tengjiang Yu
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引用次数: 0

摘要

目的 本研究旨在探讨复合改性沥青宏观流变特性的微观机理,采用灰色关系分析法(GRA)分析宏观流变指标与微观红外光谱指标之间的相关性。设计/方法/途径首先,利用动态剪切流变仪和弯曲梁流变仪分别获得了沥青(原沥青、SBS/丁苯橡胶、SBS/橡胶和SBR/橡胶)的高温和低温流变特性评价指标,并分析了其变化规律。随后,利用红外光谱测试获得了沥青的微观流变特性,并对其进行了定性和定量分析,分析了其变化规律。研究发现,SBS/橡胶复合改性沥青的抗变形性能和抗老化性能较好,复合改性剂与原生沥青的改性作用是通过物理结合实现的,其流变特性随官能团的积累而变化。研究结果揭示了复合改性剂对沥青固有改良协同效应的基本原理,为改良复合改性沥青提供了理论依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Macro-micro correlation analysis of rheological characteristics for composite modified asphalt

Purpose

This study aims to investigate the micro mechanism of macro rheological characteristics for composite modified asphalt.Grey relational analysis (GRA) was used to analyze the correlation between macro rheological indexes and micro infrared spectroscopy indexes.

Design/methodology/approach

First, a dynamic shear rheometer and a bending beam rheometer were used to obtain the evaluation indexes of high- and low-temperature rheological characteristics for asphalt (virgin, SBS/styrene butadiene rubber [SBR], SBS/rubber and SBR/rubber) respectively, and its variation rules were analyzed. Subsequently, the infrared spectroscopy test was used to obtain the micro rheological characteristics of asphalt, which were qualitatively and quantitatively analyzed, and its variation rules were analyzed. Finally, with the help of GRA, the macro-micro evaluation indexes were correlated, and the improvement efficiency of composite modifiers on asphalt was explored from rheological characteristics.

Findings

It was found that the deformation resistance and aging resistance of SBS/rubber composite modified asphalt are relatively good, and the modification effect of composite modifier and virgin asphalt is realized through physical combination, and the rheological characteristics change with the accumulation of functional groups. The correlation between macro rutting factor and micro functional group index is high, and the relationship between macro Burgers model parameters and micro functional group index is also close.

Originality/value

Results reveal the basic principle of inherent-improved synergistic effect for composite modifiers on asphalt and provide a theoretical basis for improving the composite modified asphalt.

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来源期刊
Pigment & Resin Technology
Pigment & Resin Technology 工程技术-材料科学:膜
CiteScore
2.80
自引率
21.40%
发文量
91
审稿时长
>12 weeks
期刊介绍: The journal looks at developments in: ■Adhesives and sealants ■Curing and coatings ■Wood coatings and preservatives ■Environmentally compliant coating systems and pigments ■Inks for food packaging ■Manufacturing machinery - reactors, mills mixing and dispersing equipment, pumps ■Packaging, labeling and storage ■Plus topical features and news on materials, coatings, industry people, conferences, books and so on ■Raw materials such as pigments, solvents, resins and chemicals ■Testing equipment and procedures
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