使用 S-甲基甲硫代磺酸酯作为氧化剂对富电子烯进行高效实用的氧化溴化反应

IF 1.7 4区化学 Q3 CHEMISTRY, ORGANIC

Synlett Pub Date : 2024-04-26 DOI:10.1055/s-0043-1763752

Shaolong Wang, Yong Zhou, Jianbo Wang, Ruolan Li, Chaoqun Huang, Huailin Pang, Xun Li

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引用次数: 0

摘要

以 S-甲基甲硫代磺酸酯为氧化剂，开发了一种高效实用的溴化富含电子的烯烃和杂烯烃的方法。所有的溴原子基本上都转移到了溴化产物中，这表明所提出的方案具有出色的原子经济性和实用性。该方法减少了该反应体系所需的溴用量，并能以中等至良好的产率获得产物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Highly Efficient and Practical Oxidative Bromination of Electron-Rich Arenes Using S-Methyl Methanethiosulfonate as the Oxidant

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Highly Efficient and Practical Oxidative Bromination of Electron-Rich Arenes Using S-Methyl Methanethiosulfonate as the Oxidant

An efficient and practical method for the bromination of electron-rich arenes and heteroarenes was developed by using S-methyl methanethiosulfonate as the oxidant. All the bromine atoms were basically transferred to the brominated products, demonstrating the exceptional atom economy and practicality of the proposed protocol. The method reduces the amount of bromine required for this reaction system and obtains products in moderate to good yields.

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来源期刊

Synlett 化学-有机化学

CiteScore

3.40

自引率

5.00%

发文量

369

审稿时长

1 months

期刊介绍： SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.