用于能量转换的原子级精密金属纳米团簇

IF 1.7 4区 化学
Hoeun Seong, Dongil Lee
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引用次数: 0

摘要

原子级精密金属纳米团簇(NCs)已成为电催化领域的一个新前沿,使人们能够在定义明确的稳定表面上研究电催化反应,并在原子级定制的基础上进行合理的电催化剂设计。在这篇综述中,我们将重点介绍这些 NCs 最近在能量转换反应中的应用,包括那些涉及水分离(氢和氧进化反应)、燃料电池运行(氧还原和氢氧化反应)以及二氧化碳电化学还原的反应。我们用一些具有象征意义的例子来强调不同 NC 部件(如核心金属和周围配体)的作用,以及电极基底的重要性。最后,我们讨论了基于数控技术的能源转换系统的未来发展和实施前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Atomically precise metal nanoclusters for energy conversion

Atomically precise metal nanoclusters for energy conversion

Atomically precise metal nanoclusters for energy conversion

Atomically precise metal nanoclusters (NCs) have emerged as a new frontier in electrocatalysis, enabling the study of electrocatalytic reactions on well-defined stable surfaces and rational electrocatalyst design based on atomic-level tailoring. In this review, we focus on the recent applications of these NCs to energy conversion reactions, including those involved in water splitting (hydrogen and oxygen evolution reactions), fuel cell operation (oxygen reduction and hydrogen oxidation reactions), and electrochemical CO2 reduction. Emblematic examples are used to highlight the roles of different NC parts, for example, core metal and surrounding ligands, and the significance of the electrode substrate. Finally, we discuss the perspectives of the future development and implementation of NC-based energy conversion systems.

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来源期刊
Bulletin of the Korean Chemical Society
Bulletin of the Korean Chemical Society Chemistry-General Chemistry
自引率
23.50%
发文量
182
期刊介绍: The Bulletin of the Korean Chemical Society is an official research journal of the Korean Chemical Society. It was founded in 1980 and reaches out to the chemical community worldwide. It is strictly peer-reviewed and welcomes Accounts, Communications, Articles, and Notes written in English. The scope of the journal covers all major areas of chemistry: analytical chemistry, electrochemistry, industrial chemistry, inorganic chemistry, life-science chemistry, macromolecular chemistry, organic synthesis, non-synthetic organic chemistry, physical chemistry, and materials chemistry.
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