AlH3 as High-Energy Fuels for Solid Propellants: Synthesis, Thermodynamics, Kinetics, and Stabilization

Aluminum hydride (AlH3) has attracted wide attention due to its high gravimetric and volumetric hydrogen capacity. AlH3 can easily release hydrogen when heated at relatively low temperature. Such high hydrogen density and low dehydrogenation temperature make it one of the most promising high-energy fuels for solid propellants. In particular, AlH3 as a component of solid propellants may greatly increase the specific impulse of rocket engines. However, AlH3 exhibits low chemical and thermal stability in an ambient atmosphere. In this paper, the research progress about the synthesis, dehydrogenation thermodynamics, and kinetics, the stabilization of AlH3 over the past decades are reviewed, with the aim of exploring more a economical synthesis and suitable stabilization methods for large-scale use in solid propellants. Finally, some suggestions regarding future research directions in this filed are proposed.