槿麻/环氧树脂复合材料的拉伸性能和动态力学分析

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
A. H. Abdullah, I. Tharazi, F. M. Salleh, N. H. A. Halim, Z. H. Solihin, Afeeqa Puteri Marzuki, K. Abdan
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引用次数: 0

摘要

槿麻纤维增强聚合物复合材料可以提供低成本、可生物降解、可回收和可再生的材料。与合成纤维相比,亲水性的剑麻纤维与疏水性的环氧树脂基体的相容性较差,这可能会严重制约其作为绿色复合材料的潜力。这项研究旨在评估以两种环氧树脂体系(B 树脂和 M 树脂)为基体增强的剑麻纤维复合材料的拉伸性能和动态机械分析(DMA)。研究中制作了纯环氧树脂样品和不同纤维负载量(15% 和 45%)的槿麻纤维增强复合材料。研究发现,槿叶复合材料的拉伸性能取决于环氧树脂体系,并且随着增强材料含量的增加而提高。M-15% 和 M-45% 的拉伸强度分别比同类产品高出 16.3% 和 12.0%。使用改进的微机械模型测定界面剪切强度表明,M-45 的值高于 B-45%,分别为 107.09 千帕和 90.28 千帕。通过 DMA 分析,一般来说,使用 M 树脂体系制造的槿麻复合材料的储存模量和损失模量峰值高度总是较高。根据 tan delta 曲线和科尔-科尔图计算得出的粘附系数 A 表明了每种环氧树脂体系中纤维/基体的粘附程度。扫描电子显微镜分析表明,纤维和基体周围存在空隙,这可能是由于在槿麻复合材料制造中使用的 B 树脂体系的兼容性较低。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Tensile properties and dynamic mechanical analysis of kenaf/epoxy composites
Kenaf fibre-reinforced polymer composites could offer low-cost, biodegradable, recyclable, and renewable materials. The hydrophilic kenaf fibres exhibit poor compatibility with the hydrophobic epoxy matrix as compared to their synthetic counterparts and ultimately, this may severely constrain their potential as a green composite material. This work aims to evaluate the tensile properties and dynamic mechanical analysis (DMA) of kenaf fibre composites reinforced with two epoxy systems as matrices, B and M resins. Neat epoxy samples and kenaf-reinforced composites with varying fibre loading, 15% and 45% were fabricated in the study. It was found that the tensile properties of kenaf composites are dependent on the epoxy resin systems and higher with reinforcement content. The tensile strength of M-15% and M-45% are 16.3% and 12.0% stronger than their counterparts. Determination of interfacial shear strength using a modified micromechanical model was employed showing that M-45 has a higher value than B-45%, 107.09 kPa and 90.28 kPa respectively. By DMA, in general, an increase in the storage modulus and peak height in the loss modulus was always higher with kenaf composites that were manufactured with the M resin system. The adhesion factor, A calculated from tan delta curves and cole-cole plot has shown the state of fibre/matrix adhesion level in each epoxy resin system. The SEM analysis indicates the presence of void spaces around fibres and matrix may attributed to the lower compatibility of the B resins system used in kenaf composites fabrication.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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