芙蓉花水提取物在模拟油井水中对低碳钢腐蚀的抑制作用

Balakrishnan Latha, Kaliyaperumal Kavitha, Rajendran Susai
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引用次数: 0

摘要

控制低碳钢在模拟油井水(SOWW)中的腐蚀。失重法显示,10 % v/v 的萃取物对浸泡在模拟油井水中的低碳钢(MS)具有 82 % 的抑制效率(IE)。通过极化研究和交流阻抗光谱研究了缓蚀效果的机理。极化研究表明,在抑制剂系统中存在混合型抑制剂。线性极化电阻值的增加和腐蚀电流值的降低证实了缓蚀效果。交流阻抗光谱证实了金属表面形成了保护层。电荷转移电阻值的增加和双层电容值的降低证实了这一点。抑制剂分子的吸附符合 Langmuir 吸附等温线。傅立叶变换红外光谱对保护涂层进行了表征。结果表明,抑制剂通过其活性成分 β-谷甾醇、槲皮素和山奈酚-3-木糖基葡萄糖苷与金属表面的亚铁离子配位。扫描电子显微镜(SEM)对其表面形态进行了研究。因此,芙蓉花水提取物与模拟油井水对低碳钢管道具有良好的腐蚀抑制作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Inhibition of corrosion of mild steel in simulated oil well waterby aqueous extract of Hibiscus rosa-sinensis flower
controlling the corrosion of mild steel in simulated oil well water (SOWW). Weight loss method reveals that 10 % v/v of the extract offers 82 % inhibition efficiency (IE) to mild steel (MS) immersed SOWW. The mechanistic aspects of corrosion inhibitive effect have been investigated by polarization study and AC impedance spectra. Polarization study reveals that the mixed type of inhibitor in the presence of inhibitor system. The corrosion inhibition effect is confirmed by the increase in the linear polarization resistance value and decrease in the corrosion current value. The protective layer is formed on the metal surface is confirmed by the AC impedance spectra. This is confirmed by the fact that there is increase in charge transfer resistance value and decrease in the double layer capacitance value. The adsorption of inhibitor molecule obey Langmuir adsorption isotherm. The protective coating is characterized by FTIR spectroscopy. It confirms that the inhibitor has coordinated with ferrous ion the metal surface through the active principle component of β-sitosterol, quercetin and kaempferol-3-xylosylglucoside. The surface morphology has been investigated by scanning electron microscopy (SEM). Hence, aqueous extract of Hibiscus rosa-sinensis flower with simulated oil well water good corrosive inhibitive effect on pipeline made of mild steel.
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来源期刊
Zastita materijala
Zastita materijala Materials Science-General Materials Science
CiteScore
0.80
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发文量
26
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