用简化离心纺丝法表征纳米多孔聚(乳酸)微纤维

Kazushi Yamada, C. Narita
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引用次数: 0

摘要

近年来,人们对具有优异反应性和吸附性的多孔材料的开发给予了极大关注。利用聚乳酸/氯仿溶液,通过旋转离心纺丝法成功制备了具有均匀纳米孔的聚乳酸(PLA)微纤维。以往的研究表明,聚乳酸微纤维具有极高的吸油能力。本研究系统评价了不同制备条件下纳米多孔聚乳酸微纤维的纤维直径和纳米孔径的变化以及对普鲁士蓝纳米颗粒的吸附能力。结果表明,纤维直径随聚乳酸/氯仿溶液浓度的增加而增大。此外,还发现吸附的普鲁士蓝纳米粒子的数量随着纤维直径的增加而增加。众所周知,普鲁士蓝纳米粒子可吸附铯等放射性物质,有望应用于大气和海洋中扩散的铯的回收。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Characterization of Nanoporous Poly(Lactic Acid) Microfibers Using a Simplified Centrifugal Spinning Method
In recent years, great attention has been paid to the development of porous materials with excellent reactivity and absorbency. The poly(lactic acid) (PLA) microfibers with uniform nanopores were successfully prepared by rotary centrifugal spinning using PLA/chloroform solution. Previous research showed that PLA microfibers have extremely high oil absorbing capacity. In this study, the changes in fiber diameter and nanopore diameter of nanoporous PLA microfibers under different fabrication conditions and the adsorption capacity of Prussian blue nanoparticles were systematically evaluated. The results showed that the fiber diameter increased with increasing PLA/chloroform solution concentration. Furthermore, it was found that the amount of adsorbed Prussian blue nanoparticles increased with the increase in fiber diameter. Prussian blue nanoparticles are known to adsorb radioactive materials such as cesium, and are expected to be applied to the recovery of cesium diffused in the atmosphere and ocean.
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