NaBr-RbBr 系统的热力学研究

IF 1.5 4区材料科学 Q4 CHEMISTRY, PHYSICAL

Journal of Phase Equilibria and Diffusion Pub Date : 2024-03-20 DOI:10.1007/s11669-024-01098-8

Mohamed Idbenali, Said Kardellass, M’barek Feddaoui

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引用次数: 0

摘要

本文对 NaBr-RbBr 二元体系进行了计算研究。包括相图和热力学信息在内的实验数据被用作 CALPHAD 评估的输入数据。液态和固态溶液被视为置换溶液，固态溶液（NaBr、RbBr，均为 FCC 型）被模拟为具有混溶间隙的单相。我们的计算结果与相图数据和文献中的实验热力学数据十分吻合。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Thermodynamic Investigation of the NaBr-RbBr System

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Thermodynamic Investigation of the NaBr-RbBr System

In this paper, the NaBr-RbBr binary system was computationally investigated. Experimental data including phase diagram and thermodynamic information are used as input data for the CALPHAD assessment. The liquid and solid solutions are treated as substitutional solutions and the solid solutions (NaBr, RbBr, both FCC type) were modeled as a single phase with a miscibility gap. Our calculations are in good agreement with the phase diagram data and experimental thermodynamic data available in the literature.

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来源期刊

Journal of Phase Equilibria and Diffusion 工程技术-材料科学：综合

CiteScore

2.50

自引率

7.10%

发文量

审稿时长

1 months

期刊介绍： The most trusted journal for phase equilibria and thermodynamic research, ASM International''s Journal of Phase Equilibria and Diffusion features critical phase diagram evaluations on scientifically and industrially important alloy systems, authored by international experts. The Journal of Phase Equilibria and Diffusion is critically reviewed and contains basic and applied research results, a survey of current literature and other pertinent articles. The journal covers the significance of diagrams as well as new research techniques, equipment, data evaluation, nomenclature, presentation and other aspects of phase diagram preparation and use. Content includes information on phenomena such as kinetic control of equilibrium, coherency effects, impurity effects, and thermodynamic and crystallographic characteristics. The journal updates systems previously published in the Bulletin of Alloy Phase Diagrams as new data are discovered.