二硫化物合成的现代趋势：从含金属催化剂到非物质试剂（综述）

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-03-08 DOI:10.1134/S1070328423600985

D. A. Burmistrova, I. V. Smolyaninov, N. T. Berberova

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引用次数: 0

摘要

摘要综述了制备有机对称和不对称二硫化物的合成方法的现代发展趋势。二硫化物合成的主要趋势是从涉及含金属催化剂的反应过渡到使用物理方法活化硫基质。主要关注自 2013 年至今发表的致力于在过渡和非过渡金属络合物、有机和无机氧化剂存在下，以及在电流作用、光或微波照射下合成二硫化物的研究成果。

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Modern Trends in the Synthesis of Disulfides: From Metal-Containing Catalysts to Nonmaterial Reagents (Review)

The modern trends in the development of synthetic approaches to the preparation of organic symmetrical and unsymmetrical disulfides are reviewed. The main trend in the synthesis of disulfides is the transition from the reactions involving metal-containing catalysts to the use of physical methods for the activation of sulfur substrates. The main attention is given to the works published since 2013 to the present time and devoted to the synthesis of disulfides in the presence of transition and nontransition metal complexes and organic and inorganic oxidants, as well as under the electric current action and photo- or microwave irradiation.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.