三(3-羟基丙基)膦还原六氯铱酸(IV)的反应活性:与三(2-羧乙基)膦的比较

IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
Yanhong Shi, Hongwu Tian, Zhong Liu, Siyu Shang, Meng Li, Zhiwei Zhang, Gang Ma, Li Zhou, Tiesheng Shi
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引用次数: 0

摘要

与三(2-羧乙基)膦(TCEP)相比,三(3-羟丙基)膦(THPP)被证明是一种更强的还原剂,但对其氧化动力学和机理的研究却很少。本研究 ...
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Reactivity of tris(3-hydroxypropyl)phosphine species towards reduction of hexachloroiridate(IV): a comparison with tris(2-carboxyethyl)phosphine
Tris(3-hydroxypropyl)phosphine (THPP) was shown to be a more powerful reductant than tris(2-carboxyethyl)phosphine (TCEP), but its oxidation kinetics and mechanisms were scarcely investigated. The ...
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来源期刊
Journal of Coordination Chemistry
Journal of Coordination Chemistry 化学-无机化学与核化学
CiteScore
3.60
自引率
10.50%
发文量
171
审稿时长
3.2 months
期刊介绍: The Journal of Coordination Chemistry publishes the results of original investigations of coordination complexes, loosely defined as the interactions of organic or inorganic ligands with metal centres. Original investigations may involve syntheses, structures, physical and chemical properties, kinetics and mechanisms of reactions, calculations and applications of coordination compounds. The applications may involve bioinorganic, organometallic, catalytic, solid state/materials, coordination chemistry of nanostructured surfaces and medicinal studies. The Journal publishes original manuscripts, communications and reviews. Original manuscripts are expected to provide a clear contribution to the advance of coordination chemistry. Communications are short manuscripts with an urgency that requires rapid publication. Reviews are welcome in all areas of coordination chemistry and may focus on the metal, ligand or applications. Reviews of emerging areas of coordination chemistry should be developed fully from the basics, carefully relating the topic to the field in general. Reviews of well established subjects should collect developments from the literature and take a critical view of recent work.
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