两种三唑基配位聚合物：合成与晶体结构表征

IF 2.1 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Open Chemistry Pub Date : 2024-02-28 DOI:10.1515/chem-2023-0211

Jing Li, Hongjiang Ren, Jiangtao Li, Liuchang Wang

{"title":"两种三唑基配位聚合物：合成与晶体结构表征","authors":"Jing Li, Hongjiang Ren, Jiangtao Li, Liuchang Wang","doi":"10.1515/chem-2023-0211","DOIUrl":null,"url":null,"abstract":"Here we reported two new triazole-based coordination polymers (CPs), i.e., [Zn(Hdatrz)(μ 2-O)] n (1) together with [Mn(Hdatrz)(C2O4)] n ·n(H2O) (2) (Hdatrz = 3,5-diamino-1,2,4-triazole), which were generated under solvothermal conditions. The influence of different metal ions on the structure and properties of CPs was investigated. The CPs’ whole structures have been completely characterized by the powder X-ray diffraction, Fourier transform infrared spectroscopy, and thermogravimetric analysis. It is noteworthy that, upon excitation at 390 nm, ligands of compounds 1 and 2, as well as the metal complexes, all exhibit luminescence at 432 nm.","PeriodicalId":19520,"journal":{"name":"Open Chemistry","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Two triazole-based coordination polymers: Synthesis and crystal structure characterization\",\"authors\":\"Jing Li, Hongjiang Ren, Jiangtao Li, Liuchang Wang\",\"doi\":\"10.1515/chem-2023-0211\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Here we reported two new triazole-based coordination polymers (CPs), i.e., [Zn(Hdatrz)(μ 2-O)] n (1) together with [Mn(Hdatrz)(C2O4)] n ·n(H2O) (2) (Hdatrz = 3,5-diamino-1,2,4-triazole), which were generated under solvothermal conditions. The influence of different metal ions on the structure and properties of CPs was investigated. The CPs’ whole structures have been completely characterized by the powder X-ray diffraction, Fourier transform infrared spectroscopy, and thermogravimetric analysis. It is noteworthy that, upon excitation at 390 nm, ligands of compounds 1 and 2, as well as the metal complexes, all exhibit luminescence at 432 nm.\",\"PeriodicalId\":19520,\"journal\":{\"name\":\"Open Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-02-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Open Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1515/chem-2023-0211\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Open Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/chem-2023-0211","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

在此，我们报告了在溶热条件下生成的两种新型三唑基配位聚合物（CPs），即[Zn(Hdatrz)(μ 2-O)]n（1）和[Mn(Hdatrz)(C2O4)]n -n(H2O)（2）（Hdatrz = 3,5-二氨基-1,2,4-三唑）。研究了不同金属离子对氯化石蜡结构和性质的影响。粉末 X 射线衍射、傅立叶变换红外光谱和热重分析对 CPs 的整体结构进行了完整的表征。值得注意的是，在 390 纳米波长的激发下，化合物 1 和 2 的配体以及金属复合物都在 432 纳米波长处发光。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Two triazole-based coordination polymers: Synthesis and crystal structure characterization

Here we reported two new triazole-based coordination polymers (CPs), i.e., [Zn(Hdatrz)(μ 2-O)] n (1) together with [Mn(Hdatrz)(C2O4)] n ·n(H2O) (2) (Hdatrz = 3,5-diamino-1,2,4-triazole), which were generated under solvothermal conditions. The influence of different metal ions on the structure and properties of CPs was investigated. The CPs’ whole structures have been completely characterized by the powder X-ray diffraction, Fourier transform infrared spectroscopy, and thermogravimetric analysis. It is noteworthy that, upon excitation at 390 nm, ligands of compounds 1 and 2, as well as the metal complexes, all exhibit luminescence at 432 nm.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Open Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

3.80

自引率

4.30%

发文量

审稿时长

6 weeks

期刊介绍： Open Chemistry is a peer-reviewed, open access journal that publishes original research, reviews and short communications in the fields of chemistry in an ongoing way. The central goal is to provide a hub for researchers working across all subjects to present their discoveries, and to be a forum for the discussion of the important issues in the field. The journal is the premier source for cutting edge research in fundamental chemistry and it provides high quality peer review services for its authors across the world. Moreover, it allows for libraries everywhere to avoid subscribing to multiple local publications, and to receive instead all the necessary chemistry research from a single source available to the entire scientific community.