形成稳定水油乳状液的沥青质馏分的特征

IF 0.6 4区 工程技术 Q4 ENERGY & FUELS
Yu. M. Ganeeva, E. E. Barskaya, E. S. Okhotnikova, G. R. Gazylzyanova, T. N. Yusupova, Yu. L. Karabut, R. A. Kemalov
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引用次数: 0

摘要

稳定的水油乳剂的形成是由于油/水界面上的坚固铠甲层能够阻止油中水滴的凝聚。通过将沥青质在甲苯和庚醇(正庚醇和甲苯的混合物)中的溶液与蒸馏水混合得到的水油乳状液的稳定性取决于两种沥青质馏分,即在庚醇中富含酯片段的可溶性馏分和在庚醇中容易形成聚集体的馏分。第一种馏分的表面活性剂特性允许在油/水界面形成机械强度较低的薄壳。吸附在这层薄壳上的沥青质聚集体会随着时间的推移而被压实,从而为油/水界面层带来刚性和机械强度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Characteristics of Asphaltene Fractions Responsible for the Formation of Stable Water‑Oil Emulsions

Characteristics of Asphaltene Fractions Responsible for the Formation of Stable Water‑Oil Emulsions

Stable water-oil emulsions are formed due to the strong armor layer at the oil/water interface able to prevent the coalescence of water droplets in oil. The stability of water-oil emulsions obtained by mixing solutions of asphaltene in toluene and in heptol (a mixture of n-heptanol and toluene) with distilled water was found to be a function of two asphaltene fractions, namely, a fraction soluble in heptol enriched with ester fragments and a fraction tending to form aggregates in heptol. The surfactant properties of the first fraction permit the formation of a thin shell with low mechanical strength at the oil/water interface. The asphaltene aggregates adsorbed onto this thin shell are compacted over time, imparting rigidity and mechanical strength to the oil/water interface layer.

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来源期刊
Chemistry and Technology of Fuels and Oils
Chemistry and Technology of Fuels and Oils 工程技术-工程:化工
CiteScore
0.90
自引率
16.70%
发文量
119
审稿时长
1.0 months
期刊介绍: Chemistry and Technology of Fuels and Oils publishes reports on improvements in the processing of petroleum and natural gas and cracking and refining techniques for the production of high-quality fuels, oils, greases, specialty fluids, additives and synthetics. The journal includes timely articles on the demulsification, desalting, and desulfurizing of crude oil; new flow plans for refineries; platforming, isomerization, catalytic reforming, and alkylation processes for obtaining aromatic hydrocarbons and high-octane gasoline; methods of producing ethylene, acetylene, benzene, acids, alcohols, esters, and other compounds from petroleum, as well as hydrogen from natural gas and liquid products.
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