Hao Yuan, T. Tiedje, Jingye Chen, Hui Wang, Brad Aitchison, Pawan Kumar, Yuxin Song
{"title":"用 H2S 在 Cd0.9Zn0.1Te 单晶上生长 CdS 异质结","authors":"Hao Yuan, T. Tiedje, Jingye Chen, Hui Wang, Brad Aitchison, Pawan Kumar, Yuxin Song","doi":"10.1116/6.0003265","DOIUrl":null,"url":null,"abstract":"Polished Cd0.9Zn0.1Te (CZT) single crystals have been exposed to dilute H2S in nitrogen at temperatures from 200 to 280 °C in order to produce a sulfide layer on the surface. The composition of the CZT surfaces before and after H2S exposure has been investigated by photoemission, x-ray absorption, cross-sectional SEM, and spectroscopic ellipsometry. At the highest temperature, H2S exposure removes surface oxides and depletes Te, leaving a CdS surface layer. CdS layers 60 nm thick have been grown with a 2 h exposure to H2S at 280 °C. Surfaces that are initially oxidized through ozone exposure are much more reactive with H2S than unintentionally oxidized surfaces.","PeriodicalId":282302,"journal":{"name":"Journal of Vacuum Science & Technology B","volume":"59 23","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Growth of CdS heterojunctions on Cd0.9Zn0.1Te single crystals with H2S\",\"authors\":\"Hao Yuan, T. Tiedje, Jingye Chen, Hui Wang, Brad Aitchison, Pawan Kumar, Yuxin Song\",\"doi\":\"10.1116/6.0003265\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Polished Cd0.9Zn0.1Te (CZT) single crystals have been exposed to dilute H2S in nitrogen at temperatures from 200 to 280 °C in order to produce a sulfide layer on the surface. The composition of the CZT surfaces before and after H2S exposure has been investigated by photoemission, x-ray absorption, cross-sectional SEM, and spectroscopic ellipsometry. At the highest temperature, H2S exposure removes surface oxides and depletes Te, leaving a CdS surface layer. CdS layers 60 nm thick have been grown with a 2 h exposure to H2S at 280 °C. Surfaces that are initially oxidized through ozone exposure are much more reactive with H2S than unintentionally oxidized surfaces.\",\"PeriodicalId\":282302,\"journal\":{\"name\":\"Journal of Vacuum Science & Technology B\",\"volume\":\"59 23\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Vacuum Science & Technology B\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1116/6.0003265\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Vacuum Science & Technology B","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1116/6.0003265","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Growth of CdS heterojunctions on Cd0.9Zn0.1Te single crystals with H2S
Polished Cd0.9Zn0.1Te (CZT) single crystals have been exposed to dilute H2S in nitrogen at temperatures from 200 to 280 °C in order to produce a sulfide layer on the surface. The composition of the CZT surfaces before and after H2S exposure has been investigated by photoemission, x-ray absorption, cross-sectional SEM, and spectroscopic ellipsometry. At the highest temperature, H2S exposure removes surface oxides and depletes Te, leaving a CdS surface layer. CdS layers 60 nm thick have been grown with a 2 h exposure to H2S at 280 °C. Surfaces that are initially oxidized through ozone exposure are much more reactive with H2S than unintentionally oxidized surfaces.
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