利用有机碳的平均氧化数量化布斯韦尔方程

Pong Kau Yuen, C. M. Lau
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引用次数: 1

摘要

布斯韦尔方程可以表示厌氧消化。总的化学计量方程对生物甲烷的计算和理论生化甲烷潜力非常重要。虽然有机碳氧化数的概念已在有机化学和生物化学中得到应用,但有机碳平均氧化数与生物甲烷数量之间的关系尚未得到研究。本文以 H 原子法为平衡工具,建立了一个有助于理解有机化合物氧化还原性质的布斯韦尔模型,并建立了布斯韦尔方程的化学计量系数、有机化合物的元素组成和有机碳的平均氧化数之间的数学关系。以有机碳的平均氧化数为指标,得出了生物甲烷的计算数学公式和理论生化甲烷潜能值。布斯韦尔方程的参数也可以通过任何给定的有机化合物结构式来量化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Using Mean Oxidation Number of Organic Carbons to Quantify Buswell’s Equation
Buswell’s equation can represent anaerobic digestion. The overall stoichiometric chemical equation is important for the counting of biomethane and theoretical biochemical methane potential. Although the concept of oxidation number of organic carbons has been applied in organic chemistry and biochemistry, the relationship between mean oxidation number of organic carbons and quantity of biomethane has not been studied. This article uses the H-atom method as a balancing tool to build a Buswell’s model which can help understand the redox nature of organic compounds and establish the mathematical relationships among the stoichiometric coefficients of Buswell’s equation, elemental composition of organic compound, and mean oxidation number of organic carbons. By using mean oxidation number of organic carbons as a metric, the mathematical equations for the counting of biomethane and theoretical biochemical methane potential are attained. The parameters of Buswell’s equation can also be quantified by any given structural formula of an organic compound.
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