胂中的元素回收

IF 3.3 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Bulletin of the Chemical Society of Japan Pub Date : 2024-01-17 DOI:10.1093/bulcsj/uoad028

Chisa Takahara, Suzuka Iwasaki, Yusuke Miyake, T. Yumura, Hiroaki Imoto, K. Naka

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引用次数: 0

摘要

杂原子的加入是开发先进材料的有力工具，砷（As）最近在共轭分子领域越来越受欢迎。然而，含砷材料在弃置时的潜在毒性仍然令人担忧。在本研究中，我们提出了一种胂中砷的化学回收方法。在紫外线照射下，胂的氧化开环反应可以高效进行，从而生成胂的前体--苯基胂酸。

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Element recycling in arsoles

The incorporation of heteroatoms serves as a potent tool for the development of advanced materials, and arsenic (As) has recently become increasingly popular in the field of conjugated molecules. However, the potential toxicity of As-containing materials upon disposal remains a concern. In this study, we propose a chemical recycling approach for the As in arsoles. The oxidative ring-opening reaction of arsoles proceeds efficiently under ultraviolet irradiation, leading to the production of phenylarsonic acid, a precursor of arsoles.

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来源期刊

Bulletin of the Chemical Society of Japan 化学-化学综合

CiteScore

6.40

自引率

5.00%

发文量

194

审稿时长

3-8 weeks

期刊介绍： The Bulletin of the Chemical Society of Japan (BCSJ) is devoted to the publication of scientific research papers in the fields of Theoretical and Physical Chemistry, Analytical and Inorganic Chemistry, Organic and Biological Chemistry, and Applied and Materials Chemistry. BCSJ appears as a monthly journal online and in advance with three kinds of papers (Accounts, Articles, and Short Articles) describing original research. The purpose of BCSJ is to select and publish the most important papers with the broadest significance to the chemistry community in general. The Chemical Society of Japan hopes all visitors will notice the usefulness of our journal and the abundance of topics, and welcomes more submissions from scientists all over the world.