Xuming Zhang, Weiqiang Shen, Zijun He, Ying Liu, Dandan Wang, Hua Pan, Yuzhen Jin, Zuchao Zhu, Liancheng Zhang, Kai Li
{"title":"等离子体催化正-C5H12 在 FeMn/Al2O3 催化剂上的部分氧化过程中 Mn/Fe 比率对氧代物分布的影响","authors":"Xuming Zhang, Weiqiang Shen, Zijun He, Ying Liu, Dandan Wang, Hua Pan, Yuzhen Jin, Zuchao Zhu, Liancheng Zhang, Kai Li","doi":"10.1007/s11090-024-10445-z","DOIUrl":null,"url":null,"abstract":"<div><p>Oxygenates production from the partial oxidation of liquid fuel is required for a cleaner combustion. The effect of Mn/Fe ratio was investigated to improve the oxygenates formation via plasma catalytic n-C<sub>5</sub>H<sub>12</sub> partial oxidation over FeMn/Al<sub>2</sub>O<sub>3</sub> catalyst. The oxygenates selectivities exhibited a volcano shape with the Mn/Fe ratio and the highest value of 69% was obtained at Mn/Fe ratio of 7/3. The oxygenates selectivities were dominated by both the acidity and active oxygen species of catalyst, which could be tuned by Mn/Fe ratio. A close relationship between oxygenates selectivities, acidity, and active oxygen species of catalyst was established. The higher the active oxygen species content and the lower the acidity, the higher the oxygenates selectivities.</p></div>","PeriodicalId":734,"journal":{"name":"Plasma Chemistry and Plasma Processing","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2024-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Effect of Mn/Fe Ratio on the Oxygenates Distribution from Partial Oxidation of n-C5H12 by Plasma Catalysis Over FeMn/Al2O3 Catalyst\",\"authors\":\"Xuming Zhang, Weiqiang Shen, Zijun He, Ying Liu, Dandan Wang, Hua Pan, Yuzhen Jin, Zuchao Zhu, Liancheng Zhang, Kai Li\",\"doi\":\"10.1007/s11090-024-10445-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Oxygenates production from the partial oxidation of liquid fuel is required for a cleaner combustion. The effect of Mn/Fe ratio was investigated to improve the oxygenates formation via plasma catalytic n-C<sub>5</sub>H<sub>12</sub> partial oxidation over FeMn/Al<sub>2</sub>O<sub>3</sub> catalyst. The oxygenates selectivities exhibited a volcano shape with the Mn/Fe ratio and the highest value of 69% was obtained at Mn/Fe ratio of 7/3. The oxygenates selectivities were dominated by both the acidity and active oxygen species of catalyst, which could be tuned by Mn/Fe ratio. A close relationship between oxygenates selectivities, acidity, and active oxygen species of catalyst was established. The higher the active oxygen species content and the lower the acidity, the higher the oxygenates selectivities.</p></div>\",\"PeriodicalId\":734,\"journal\":{\"name\":\"Plasma Chemistry and Plasma Processing\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-01-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Plasma Chemistry and Plasma Processing\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11090-024-10445-z\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plasma Chemistry and Plasma Processing","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11090-024-10445-z","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
The Effect of Mn/Fe Ratio on the Oxygenates Distribution from Partial Oxidation of n-C5H12 by Plasma Catalysis Over FeMn/Al2O3 Catalyst
Oxygenates production from the partial oxidation of liquid fuel is required for a cleaner combustion. The effect of Mn/Fe ratio was investigated to improve the oxygenates formation via plasma catalytic n-C5H12 partial oxidation over FeMn/Al2O3 catalyst. The oxygenates selectivities exhibited a volcano shape with the Mn/Fe ratio and the highest value of 69% was obtained at Mn/Fe ratio of 7/3. The oxygenates selectivities were dominated by both the acidity and active oxygen species of catalyst, which could be tuned by Mn/Fe ratio. A close relationship between oxygenates selectivities, acidity, and active oxygen species of catalyst was established. The higher the active oxygen species content and the lower the acidity, the higher the oxygenates selectivities.
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Publishing original papers on fundamental and applied research in plasma chemistry and plasma processing, the scope of this journal includes processing plasmas ranging from non-thermal plasmas to thermal plasmas, and fundamental plasma studies as well as studies of specific plasma applications. Such applications include but are not limited to plasma catalysis, environmental processing including treatment of liquids and gases, biological applications of plasmas including plasma medicine and agriculture, surface modification and deposition, powder and nanostructure synthesis, energy applications including plasma combustion and reforming, resource recovery, coupling of plasmas and electrochemistry, and plasma etching. Studies of chemical kinetics in plasmas, and the interactions of plasmas with surfaces are also solicited. It is essential that submissions include substantial consideration of the role of the plasma, for example, the relevant plasma chemistry, plasma physics or plasma–surface interactions; manuscripts that consider solely the properties of materials or substances processed using a plasma are not within the journal’s scope.
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