D. Bissinger, J. H. Honerkamp, J. Roldan, J. Bremes, K. Kannen, M. K. Lake, A. Roppertz
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引用次数: 0
摘要
在工业流程(如垃圾焚烧)中,必须减少固体成分(如粉尘或飞灰)和气体成分(如二恶英、一氧化碳和其他有害碳氢化合物),以满足法律要求。因此,基于聚合物的催化功能化过滤器已经存在。不过,众所周知,此类过滤器通常采用多层结构,以防止催化剂颗粒的迁移。本研究表明,利用火焰喷射热解技术可以制备出基于聚酯针刺毡的稳定催化功能化单层过滤器。催化剂为低温活性 Pt/TiO2,在过滤器上的负载重量为 38 克/升。通过扫描电子显微镜(SEM)图像,证明了催化剂颗粒的均匀分布,甚至在单层过滤器的深层区域也是如此。在实际条件下进行的实验也证实了这一结构--不会发生迁移。同样,在低于 100 °C 的温度下,一氧化碳(CO)也能完全氧化转化为二氧化碳(CO2)。此外,与蜂窝和陶瓷泡沫上的催化剂进行的比较研究表明,聚酯针刺毡织物催化剂上的转化率相当。
Development of Catalytically Functionalized Polyester-Based Filters Produced by Flame Spray Pyrolysis
For industrial processes—like waste incineration—it is necessary to reduce solid components (like dust or fly ash) as well as gaseous components (like dioxins, CO and other harmful hydrocarbons) to fulfill legal requirements. Therefore, catalytically functionalized filters based on polymers already exist. However, it is known that such filters are always constructed in multiple layers to prevent the migration of catalyst particles. This study demonstrates that it is possible to prepare a stable catalytic functionalized single-layer filter based on polyester needle felt by using flame spray pyrolysis. The catalyst is a low temperature active Pt/TiO2 with a loading weight of 38 g/l on the filter. Via SEM images the uniform distribution of the catalytic particles even in the deeper regions of the single-layer filter was proven. The structure was confirmed after experiments under realistic conditions—migration could not be obtained. Likewise, it was obtained that the oxidative conversion of carbon monoxide (CO) to carbon dioxide (CO2) is completely even at temperatures below 100 °C. Furthermore, comparative studies with catalysts on a honeycomb and a ceramic foam have shown that the conversion on the polyester needle felt textile catalyst is comparable.
期刊介绍:
Topics in Catalysis publishes topical collections in all fields of catalysis which are composed only of invited articles from leading authors. The journal documents today’s emerging and critical trends in all branches of catalysis. Each themed issue is organized by renowned Guest Editors in collaboration with the Editors-in-Chief. Proposals for new topics are welcome and should be submitted directly to the Editors-in-Chief.
The publication of individual uninvited original research articles can be sent to our sister journal Catalysis Letters. This journal aims for rapid publication of high-impact original research articles in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis.