{"title":"4-乙烯基苄基苯砜的合成与聚合","authors":"I. Abu-Abdoun","doi":"10.6000/1929-5995.2023.12.16","DOIUrl":null,"url":null,"abstract":"The preparation of new sulfone monomer and polymer based on 4-Vinylbenzylphenylsulfone (4-VBPS) and free radical polymerization was investigated, based on the reaction of chloromethyl styrene with sodium phenyl sulfone (phSO2Na) in dimethylformamide (DMF), using the phase transfer catalysts 18-crown-6. Copolymerization of the prepared sulphone monomer with p-methylstyrene was carried out at 65 ˚C. Nonpolymerizable 4-Ethylbenzylphenylsulfone was also prepared. The prepared monomers and polymers were characterized by different spectroscopic techniques, the number-average molecular weights (Mn) of the resulting polymer was found to be in the range of 70,100 -73,100, with polydispersity indices (Mw/Mn) vary from 1.8 to 1.9. Photolysis of the prepared polysulfone polymer and possible grafting of methyl methacrylate (MMA) monomer will be reported.","PeriodicalId":16998,"journal":{"name":"Journal of Research Updates in Polymer Science","volume":"259 3","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Polymerization of 4-Vinylbenzylphenylsulfone\",\"authors\":\"I. Abu-Abdoun\",\"doi\":\"10.6000/1929-5995.2023.12.16\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The preparation of new sulfone monomer and polymer based on 4-Vinylbenzylphenylsulfone (4-VBPS) and free radical polymerization was investigated, based on the reaction of chloromethyl styrene with sodium phenyl sulfone (phSO2Na) in dimethylformamide (DMF), using the phase transfer catalysts 18-crown-6. Copolymerization of the prepared sulphone monomer with p-methylstyrene was carried out at 65 ˚C. Nonpolymerizable 4-Ethylbenzylphenylsulfone was also prepared. The prepared monomers and polymers were characterized by different spectroscopic techniques, the number-average molecular weights (Mn) of the resulting polymer was found to be in the range of 70,100 -73,100, with polydispersity indices (Mw/Mn) vary from 1.8 to 1.9. Photolysis of the prepared polysulfone polymer and possible grafting of methyl methacrylate (MMA) monomer will be reported.\",\"PeriodicalId\":16998,\"journal\":{\"name\":\"Journal of Research Updates in Polymer Science\",\"volume\":\"259 3\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-11-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Research Updates in Polymer Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.6000/1929-5995.2023.12.16\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Research Updates in Polymer Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.6000/1929-5995.2023.12.16","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Polymerization of 4-Vinylbenzylphenylsulfone
The preparation of new sulfone monomer and polymer based on 4-Vinylbenzylphenylsulfone (4-VBPS) and free radical polymerization was investigated, based on the reaction of chloromethyl styrene with sodium phenyl sulfone (phSO2Na) in dimethylformamide (DMF), using the phase transfer catalysts 18-crown-6. Copolymerization of the prepared sulphone monomer with p-methylstyrene was carried out at 65 ˚C. Nonpolymerizable 4-Ethylbenzylphenylsulfone was also prepared. The prepared monomers and polymers were characterized by different spectroscopic techniques, the number-average molecular weights (Mn) of the resulting polymer was found to be in the range of 70,100 -73,100, with polydispersity indices (Mw/Mn) vary from 1.8 to 1.9. Photolysis of the prepared polysulfone polymer and possible grafting of methyl methacrylate (MMA) monomer will be reported.
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