分子氢原位转化的异质催化剂探索

Hideki Abe, Hiroshi Mizoguchi, Ryuto Eguchi, Hideo Hosono
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引用次数: 0

摘要

分子氢(H2)的正副转化(O/P 转化)在低温下进行缓慢,并伴有热量释放。因此,在液态氢的储存和利用方面,加快这种转化率的催化剂需求量很大。为此,我们通过对磁性、非磁性、金属和非金属氧化物等多种材料的研究,对催化剂进行了实验筛选。得出的主要结论概述如下。(1) 活性材料必须是非金属材料,并含有离子半径小于 H2 键长的阳离子。(2) 金属材料无论是否具有磁性,几乎都没有活性 (3) 当构成材料的阳离子具有磁矩时,属于(1)的材料的活性会大大增强。此外,还有一类材料在被外来离子取代后,其活性会明显增强。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Exploration of heterogeneous catalyst for molecular hydrogen ortho-para conversion

Exploration of heterogeneous catalyst for molecular hydrogen ortho-para conversion

Molecular hydrogen (H2) ortho-para conversion (O/P conversion) proceeds slowly at low temperatures accompanying a heat release. Thus, catalysts for accelerating this conversion rate are highly demanded in terms of the storage and utilization of liquid H2. The catalysts for this purpose are experimentally screened by examining a broad range of materials covering magnetic, non-magnetic, metallic, and nonmetallic oxides. The primary conclusions obtained are summarized below. (1) active materials are required to be non-metallic and to bear the cations with ionic radii smaller than the bond length of H2. (2) Metallic materials have almost no activity irrespective of with or without magnetism (3) The activity of materials belonging to (1) is largely enhanced when the constituting cation has a magnetic moment. In addition, there is a class of materials for which the activity is distinctly enhanced just upon substitution by the foreign ions.

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