Electrochromic Polymers: From Electrodeposition to Hybrid Solid Devices

This paper reports on the linear colorimetric and electrochromic (EC) characteristics of electrodeposited polyaniline (PANI) films. This paper also investigates the infrared EC properties of acid-doped PANI films. The electrochemical polymerization method was employed to create a porous and thin PANI film layer onto PET-ITO substrates. This layer was capped with WO3 film to create a gel electrolyte sandwich structure that demonstrates the compatibility of PANI films with cathodic WO3 films in full devices. The electrodeposition of the film was fabricated by applying different voltages and time, with the optimal film quality achieved with the 1.7 V voltage and a 20 min deposition period. The surface morphology, optical performance, electrochemical behavior, and molecular structure evolution are comprehensively studied in this work. The linear colorimetric behaviors and the corresponding significant changes in the structure in Raman spectra build direct strong quantitative relations in EC polymers. The well-defined oxidation and reduction peaks observed in the cyclic voltammetry indicate the ion-diffusion dominant process in the electrochromism of PANI. Significant transitions between the benzene and quinone phases in the Raman spectra are found in the bleached and colored states of polymers. This study enhances the understanding of PANI film structure and electrochemical and associated optical properties, providing more insights into the dual-function EC charge storage polymers and other energy-related functional materials.