{"title":"盐酸中 Ghars 红枣提取物对 API 5L X70 管道钢的缓蚀效率","authors":"Slimane Kherief, Mounir Djellab, Hamza Bentrah, Abdelouahad Chala, Bouzid Bouamra, Hicham Taoui","doi":"10.1134/S2070205123701162","DOIUrl":null,"url":null,"abstract":"<p>The inability to produce raw materials in sufficient quantities, such as fruits, plants, pigments and resins, to manufacture green inhibitors is considered one of the biggest reasons that hinder the commercial use of these eco-friendly inhibitors. In Asia and Africa, date fruit is produced in large quantities. This fruit contains polysaccharides (primarily galacturonic acid) that can be used as a green inhibitor. The inhibition effect of Ghars date extract (GDE) on the corrosion of API 5L X70 pipeline steel in 0.5 M HCl solution was studied for the first time using electrochemical impedance spectroscopy, potentiodynamic polarization curves, scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The results show that GDE is an excellent inhibitor. The inhibition efficiency was 94 % at 2 g/L GDE. The GDE follows the Langmuir adsorption isotherm and involves physical adsorption. The GDE acts as a mixed-type inhibitor.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"59 6","pages":"1306 - 1314"},"PeriodicalIF":1.1000,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Corrosion Inhibition Efficiency of Ghars Date Extract on API 5L X70 Pipeline Steel in Hydrochloric Acid\",\"authors\":\"Slimane Kherief, Mounir Djellab, Hamza Bentrah, Abdelouahad Chala, Bouzid Bouamra, Hicham Taoui\",\"doi\":\"10.1134/S2070205123701162\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The inability to produce raw materials in sufficient quantities, such as fruits, plants, pigments and resins, to manufacture green inhibitors is considered one of the biggest reasons that hinder the commercial use of these eco-friendly inhibitors. In Asia and Africa, date fruit is produced in large quantities. This fruit contains polysaccharides (primarily galacturonic acid) that can be used as a green inhibitor. The inhibition effect of Ghars date extract (GDE) on the corrosion of API 5L X70 pipeline steel in 0.5 M HCl solution was studied for the first time using electrochemical impedance spectroscopy, potentiodynamic polarization curves, scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The results show that GDE is an excellent inhibitor. The inhibition efficiency was 94 % at 2 g/L GDE. The GDE follows the Langmuir adsorption isotherm and involves physical adsorption. The GDE acts as a mixed-type inhibitor.</p>\",\"PeriodicalId\":745,\"journal\":{\"name\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"volume\":\"59 6\",\"pages\":\"1306 - 1314\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2023-12-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2070205123701162\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Protection of Metals and Physical Chemistry of Surfaces","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S2070205123701162","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
摘要
摘要 无法生产足够数量的原材料(如水果、植物、颜料和树脂)来制造绿色抑制剂,被认为是阻碍这些生态友好型抑制剂商业化应用的最大原因之一。在亚洲和非洲,椰枣果实产量很大。这种水果含有可用作绿色抑制剂的多糖(主要是半乳糖醛酸)。利用电化学阻抗光谱、电位极化曲线、扫描电子显微镜(SEM)和能量色散 X 射线光谱(EDX),首次研究了 Ghars 椰枣提取物(GDE)对 API 5L X70 管线钢在 0.5 M HCl 溶液中的腐蚀抑制效果。结果表明,GDE 是一种出色的抑制剂。2 g/L GDE 的抑制效率为 94%。GDE 遵循 Langmuir 吸附等温线,具有物理吸附作用。GDE 是一种混合型抑制剂。
Corrosion Inhibition Efficiency of Ghars Date Extract on API 5L X70 Pipeline Steel in Hydrochloric Acid
The inability to produce raw materials in sufficient quantities, such as fruits, plants, pigments and resins, to manufacture green inhibitors is considered one of the biggest reasons that hinder the commercial use of these eco-friendly inhibitors. In Asia and Africa, date fruit is produced in large quantities. This fruit contains polysaccharides (primarily galacturonic acid) that can be used as a green inhibitor. The inhibition effect of Ghars date extract (GDE) on the corrosion of API 5L X70 pipeline steel in 0.5 M HCl solution was studied for the first time using electrochemical impedance spectroscopy, potentiodynamic polarization curves, scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The results show that GDE is an excellent inhibitor. The inhibition efficiency was 94 % at 2 g/L GDE. The GDE follows the Langmuir adsorption isotherm and involves physical adsorption. The GDE acts as a mixed-type inhibitor.
期刊介绍:
Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.