甲基丙烯酸月桂酯在合成聚α烯烃基础油中的受控辐射聚合反应

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Doklady Chemistry Pub Date : 2023-12-25 DOI:10.1134/S0012500823600712

E. V. Chernikova, M. S. Pavlova, A. V. Plutalova, E. A. Litmanovich, A. L. Maksimov

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引用次数: 0

摘要

摘要在 2-氰基-2-丙基十二烷基三硫代碳酸酯存在下，首次实现了甲基丙烯酸月桂酯在聚α烯烃基础油中的受控自由基聚合。结果表明，聚合反应的单体转化率很高，形成的聚合物分子量分布较窄。同时，反应混合物在聚合完成后仍保持透明度。合成的聚合物具有增稠能力，这种能力随着其平均分子量的增加而自然增强。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Controlled Radical Polymerization of Lauryl Methacrylate in the Synthetic Polyalphaolefin Base Oil

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Controlled Radical Polymerization of Lauryl Methacrylate in the Synthetic Polyalphaolefin Base Oil

Controlled radical polymerization of lauryl methacrylate in polyalphaolefin base oil has been performed for the first time in the presence of 2-cyano-2-propyl dodecyl trithiocarbonate. It has been shown that polymerization proceeds to high monomer conversions and leads to the formation of a polymer with a narrow molecular weight distribution. At the same time, the reaction mixtures retain their transparency after polymerization is completed. The synthesized polymers have a thickening ability, which naturally increases with an increase in their number-average molecular weight.

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来源期刊

Doklady Chemistry 化学-化学综合

CiteScore

1.20

自引率

12.50%

发文量

审稿时长

6-12 weeks

期刊介绍： Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.