双(2,6-二(吡啶-2-基)吡啶-4-基)-6,6′-(1,2-二壬二基)二己酸酯。

IF 0.6 Q4 CHEMISTRY, ORGANIC

Molbank Pub Date : 2023-12-20 DOI:10.3390/m1752

E. Popa, A. Andelescu, Valentin Badea, Paula Svera M Ianăşi, Elisabeta I. Szerb

{"title":"双(2,6-二(吡啶-2-基)吡啶-4-基)-6,6′-(1,2-二壬二基)二己酸酯。","authors":"E. Popa, A. Andelescu, Valentin Badea, Paula Svera M Ianăşi, Elisabeta I. Szerb","doi":"10.3390/m1752","DOIUrl":null,"url":null,"abstract":"The present paper describes the preparation and characterization of a new dinuclear ligand based on terpyridine featuring a diselenide unit. This new compound was synthesized in a two-step procedure that first involved the insertion of the diselenide moiety on a carboxylic acid and was followed by a Steglich esterification reaction between the biscarboxylic acid containing the diselenide unit and 2,6-di(pyridin-2-yl)pyridin-4-ol (tpyOH). The title compound was characterized via FT-IR, Raman, NMR (1D and 2D), and UV-Vis spectroscopies and elemental analysis. Emission properties were investigated.","PeriodicalId":18761,"journal":{"name":"Molbank","volume":"105 17","pages":""},"PeriodicalIF":0.6000,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bis(2,6-di(pyridin-2-yl)pyridin-4-yl)-6,6′-(1,2-diselanediyl)dihexanoate\",\"authors\":\"E. Popa, A. Andelescu, Valentin Badea, Paula Svera M Ianăşi, Elisabeta I. Szerb\",\"doi\":\"10.3390/m1752\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The present paper describes the preparation and characterization of a new dinuclear ligand based on terpyridine featuring a diselenide unit. This new compound was synthesized in a two-step procedure that first involved the insertion of the diselenide moiety on a carboxylic acid and was followed by a Steglich esterification reaction between the biscarboxylic acid containing the diselenide unit and 2,6-di(pyridin-2-yl)pyridin-4-ol (tpyOH). The title compound was characterized via FT-IR, Raman, NMR (1D and 2D), and UV-Vis spectroscopies and elemental analysis. Emission properties were investigated.\",\"PeriodicalId\":18761,\"journal\":{\"name\":\"Molbank\",\"volume\":\"105 17\",\"pages\":\"\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2023-12-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Molbank\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/m1752\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Molbank","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/m1752","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}

引用次数: 0

摘要

本文介绍了一种新的双核配体的制备和表征，该配体以具有二硒化单元的三联吡啶为基础。这种新化合物的合成分两步进行，首先将二硒化物插入羧酸中，然后在含有二硒化物单元的双羧酸和 2,6-二(吡啶-2-基)吡啶-4-醇 (tpyOH) 之间进行斯特克里奇酯化反应。通过傅立叶变换红外光谱、拉曼光谱、核磁共振（一维和二维）光谱、紫外-可见光谱和元素分析对标题化合物进行了表征。还对发射特性进行了研究。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Bis(2,6-di(pyridin-2-yl)pyridin-4-yl)-6,6′-(1,2-diselanediyl)dihexanoate

The present paper describes the preparation and characterization of a new dinuclear ligand based on terpyridine featuring a diselenide unit. This new compound was synthesized in a two-step procedure that first involved the insertion of the diselenide moiety on a carboxylic acid and was followed by a Steglich esterification reaction between the biscarboxylic acid containing the diselenide unit and 2,6-di(pyridin-2-yl)pyridin-4-ol (tpyOH). The title compound was characterized via FT-IR, Raman, NMR (1D and 2D), and UV-Vis spectroscopies and elemental analysis. Emission properties were investigated.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)