作为碱性制氢主要电催化材料的过渡金属磷化物

IF 7.9 2区 综合性期刊 Q1 CHEMISTRY, MULTIDISCIPLINARY
S.K. Tarik Aziz, Sabiha Sultana, Ashwani Kumar, Sk. Riyajuddin, Manodip Pal, Arnab Dutta
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引用次数: 0

摘要

随着人们对可再生能源的兴趣与日俱增,以及各行各业对去碳化的迫切需求,具有成本效益的碱性水电解技术已成为生产绿色氢燃料的高效能源转换的关键技术。过渡金属磷化物(TMPs)具有类金属特性、丰富的资产、可调的成分、优异的导电性和成本效益等优点,是公认的具有吸引力的碱性电解槽催化材料。本文全面总结了过渡金属磷化物(镍和钴)及其标准合成方法的最新研究进展,以及单金属到双金属磷化物(镍钴)的作用。此外,还对不同磷化物的催化氢进化反应活性进行了比较研究,强调了能效、反应动力学和表面反应热力学的重要性。对 TMPs 的电子和结构特性进行适当的调整可显著提高其效率,从而发挥其在通过碱性水电解扩大碳中和制氢规模方面的巨大潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Transition metal phosphides as cardinal electrocatalytic materials for alkaline hydrogen production

Transition metal phosphides as cardinal electrocatalytic materials for alkaline hydrogen production

Amid the growing interest in renewable energy sources and the urgent need for decarbonization in various industries, cost-effective alkaline water electrolysis has emerged as a pivotal technology enabling efficient energy conversion to produce green hydrogen fuel. With the merits of metalloid character, abundant assets, tunable composition, superior conductivity, and cost-effectiveness, transition metal phosphides (TMPs) are recognized as attractive catalytic materials for alkaline electrolyzers. Here, the recent research progress on TMPs (Ni and Co) with their standard synthetic methodology and the roles of mono to bimetallic phosphides (Ni–Co) have been comprehensively summarized. A comparative study of the catalytic hydrogen evolution reaction activity of different phosphides is also included, where the importance of energy efficiency, reaction kinetics, and surface reaction thermodynamics is emphasized. The apt tuning of the electronic and structural properties of TMPs can significantly boost their efficiency to fulfill their tremendous potential in scaling up carbon-neutral hydrogen production via alkaline water electrolysis.

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来源期刊
Cell Reports Physical Science
Cell Reports Physical Science Energy-Energy (all)
CiteScore
11.40
自引率
2.20%
发文量
388
审稿时长
62 days
期刊介绍: Cell Reports Physical Science, a premium open-access journal from Cell Press, features high-quality, cutting-edge research spanning the physical sciences. It serves as an open forum fostering collaboration among physical scientists while championing open science principles. Published works must signify significant advancements in fundamental insight or technological applications within fields such as chemistry, physics, materials science, energy science, engineering, and related interdisciplinary studies. In addition to longer articles, the journal considers impactful short-form reports and short reviews covering recent literature in emerging fields. Continually adapting to the evolving open science landscape, the journal reviews its policies to align with community consensus and best practices.
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