{"title":"稀释剂的性质对 N,N,N',N'-四丁基二乙二醇酰胺提取 Eu(III)、Am(III) 和 Cm(III) 的能力的影响","authors":"V. E. Sharov, G. V. Kostikova","doi":"10.1134/S106636222305003X","DOIUrl":null,"url":null,"abstract":"<p>The effect of HNO<sub>3</sub> concentration on the extraction of Eu(III), Am(III), and Cm(III) with <i>N</i>,<i>N</i>,<i>N</i>',<i>N</i>'-tetrabutyldiglycolamide was studied in 5 different diluents: nitrobenzene, toluene, chloroform, 1,2-dichloroethane, and 1,1,2,2-tetrachloroethane. The distribution coefficients of these metals as a function of the nature of the diluent in the following series of compounds was established: nitrobenzene > <i>m</i>-trifluoromethylnitrobenzene > mixture of <i>n</i>-dodecane with decanol-1 (volume ratio 90 : 10) > carbon tetrachloride > 1,2-dichloroethane > benzene > 1,1,2,2-tetrachloroethane > toluene > chloroform. The conditions for the partioning Eu(III)/Am(III) and Am(III)/Cm(III) pairs were found. An explanation was proposed for the observed increase in the separation factors of the Am(III)/Cm(III) pair with increasing concentration of nitric acid in the equilibrium aqueous phase.</p>","PeriodicalId":747,"journal":{"name":"Radiochemistry","volume":null,"pages":null},"PeriodicalIF":0.9000,"publicationDate":"2023-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of the Nature of Diluent on the Extractability of N,N,N',N'-Tetrabutyldiglycolamide for Eu(III), Am(III), and Cm(III)\",\"authors\":\"V. E. Sharov, G. V. Kostikova\",\"doi\":\"10.1134/S106636222305003X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The effect of HNO<sub>3</sub> concentration on the extraction of Eu(III), Am(III), and Cm(III) with <i>N</i>,<i>N</i>,<i>N</i>',<i>N</i>'-tetrabutyldiglycolamide was studied in 5 different diluents: nitrobenzene, toluene, chloroform, 1,2-dichloroethane, and 1,1,2,2-tetrachloroethane. The distribution coefficients of these metals as a function of the nature of the diluent in the following series of compounds was established: nitrobenzene > <i>m</i>-trifluoromethylnitrobenzene > mixture of <i>n</i>-dodecane with decanol-1 (volume ratio 90 : 10) > carbon tetrachloride > 1,2-dichloroethane > benzene > 1,1,2,2-tetrachloroethane > toluene > chloroform. The conditions for the partioning Eu(III)/Am(III) and Am(III)/Cm(III) pairs were found. An explanation was proposed for the observed increase in the separation factors of the Am(III)/Cm(III) pair with increasing concentration of nitric acid in the equilibrium aqueous phase.</p>\",\"PeriodicalId\":747,\"journal\":{\"name\":\"Radiochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2023-12-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S106636222305003X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiochemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S106636222305003X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Influence of the Nature of Diluent on the Extractability of N,N,N',N'-Tetrabutyldiglycolamide for Eu(III), Am(III), and Cm(III)
The effect of HNO3 concentration on the extraction of Eu(III), Am(III), and Cm(III) with N,N,N',N'-tetrabutyldiglycolamide was studied in 5 different diluents: nitrobenzene, toluene, chloroform, 1,2-dichloroethane, and 1,1,2,2-tetrachloroethane. The distribution coefficients of these metals as a function of the nature of the diluent in the following series of compounds was established: nitrobenzene > m-trifluoromethylnitrobenzene > mixture of n-dodecane with decanol-1 (volume ratio 90 : 10) > carbon tetrachloride > 1,2-dichloroethane > benzene > 1,1,2,2-tetrachloroethane > toluene > chloroform. The conditions for the partioning Eu(III)/Am(III) and Am(III)/Cm(III) pairs were found. An explanation was proposed for the observed increase in the separation factors of the Am(III)/Cm(III) pair with increasing concentration of nitric acid in the equilibrium aqueous phase.
期刊介绍:
Radiochemistry is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.