Lingting Xia, Han Wu, Jing Gao, Tianzhen Ye, Long Qiu, Feize Li, Tu Lan, Jijun Yang, Jiali Liao, Ning Liu, Yuanyou Yang
{"title":"新型无溶剂有机分离工艺从辐照镓镍合金中高效提取68Ge","authors":"Lingting Xia, Han Wu, Jing Gao, Tianzhen Ye, Long Qiu, Feize Li, Tu Lan, Jijun Yang, Jiali Liao, Ning Liu, Yuanyou Yang","doi":"10.1515/ract-2023-0161","DOIUrl":null,"url":null,"abstract":"In this work, a gallium–nickel alloy target with a weight percentage ratio of 7:3 was successfully prepared on Cu substrate in a chloride system at room temperature. A novel organic-solvent-free separation procedure based on two columns for extracting <jats:sup>68</jats:sup>Ge from irradiated Ga–Ni alloy target with high radionuclidic purity (99.99 %) was developed. By this separation procedure, the recovery of <jats:sup>68</jats:sup>Ge is 95 ± 5 % and the yield of <jats:sup>68</jats:sup>Ge via the nuclear reaction <jats:sup>nat</jats:sup>Ga(p,<jats:italic>x</jats:italic>n)<jats:sup>68</jats:sup>Ge was measured to be 0.27 ± 0.02 MBq/μA h.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Efficient extraction of 68Ge from irradiated Ga–Ni alloy via a novel organic-solvent-free separation procedure\",\"authors\":\"Lingting Xia, Han Wu, Jing Gao, Tianzhen Ye, Long Qiu, Feize Li, Tu Lan, Jijun Yang, Jiali Liao, Ning Liu, Yuanyou Yang\",\"doi\":\"10.1515/ract-2023-0161\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this work, a gallium–nickel alloy target with a weight percentage ratio of 7:3 was successfully prepared on Cu substrate in a chloride system at room temperature. A novel organic-solvent-free separation procedure based on two columns for extracting <jats:sup>68</jats:sup>Ge from irradiated Ga–Ni alloy target with high radionuclidic purity (99.99 %) was developed. By this separation procedure, the recovery of <jats:sup>68</jats:sup>Ge is 95 ± 5 % and the yield of <jats:sup>68</jats:sup>Ge via the nuclear reaction <jats:sup>nat</jats:sup>Ga(p,<jats:italic>x</jats:italic>n)<jats:sup>68</jats:sup>Ge was measured to be 0.27 ± 0.02 MBq/μA h.\",\"PeriodicalId\":21167,\"journal\":{\"name\":\"Radiochimica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2023-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiochimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1515/ract-2023-0161\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiochimica Acta","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/ract-2023-0161","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Efficient extraction of 68Ge from irradiated Ga–Ni alloy via a novel organic-solvent-free separation procedure
In this work, a gallium–nickel alloy target with a weight percentage ratio of 7:3 was successfully prepared on Cu substrate in a chloride system at room temperature. A novel organic-solvent-free separation procedure based on two columns for extracting 68Ge from irradiated Ga–Ni alloy target with high radionuclidic purity (99.99 %) was developed. By this separation procedure, the recovery of 68Ge is 95 ± 5 % and the yield of 68Ge via the nuclear reaction natGa(p,xn)68Ge was measured to be 0.27 ± 0.02 MBq/μA h.