在0.5 mol L−1 H2SO4中,细木叶提取物对纯铁的缓蚀作用:基于实验和GC-MS的研究

IF 1.2 4区 工程技术 Q4 CHEMISTRY, APPLIED
Xuxiang Wang, Fuyan Wang, Xianyu Pan, Jing Hu, Jing Liu
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引用次数: 0

摘要

本研究采用水浸法提取薄荷叶提取物(ELE)的官能团,并用红外光谱(FTIR)进行鉴定。采用失重法、电化学行为和金属表面形貌检测等测试方法,研究了天然植物缓蚀剂ELE在0.5 mol L−1 H2SO4溶液中对纯铁的缓蚀效果。结果表明:在0.5 mol L−1 H2SO4溶液中,ELE对纯铁的腐蚀行为有正向抑制作用,且ELE浓度越高,其抑制作用越大;在高温下仍可达83.97%。SEM检测和接触角测量结果表明,加入ELE后金属的腐蚀程度明显降低,金属表面的疏水性增强。ELE在纯铁表面的吸附趋于等温Langmuir吸附,作为混合缓蚀剂,体系的电荷转移电阻显著增大,电双层的电容值显著降低。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Corrosion inhibition of pure iron by Eurohypnum leptothallum extract in 0.5 mol L−1 H2SO4: an experimental and GC-MS based study
In this work, the functional groups of Eurohypnum leptothallum extract (ELE) were extracted by aqueous immersion and identified by FTIR. The corrosion inhibitory effect of ELE as a natural plant corrosion inhibitor on pure iron in 0.5 mol L−1 H2SO4 solution was investigated by test methods such as the weight loss method, electrochemical behaviour and detection of metal surface topography. The results show that ELE has a positive inhibitory effect on the corrosion behaviour of pure iron in 0.5 mol L−1 H2SO4 solution, and the higher the concentration of ELE, the greater the corrosion inhibitory effect. It can still reach 83.97 % at high temperatures. The results of SEM examination and contact angle measurements show that the corrosion degree of the metal decreases significantly after the additon of ELE and that the hydrophobicity of the metal surface increases. The adsorption of ELE on the surface of pure iron tends to isothermal Langmuir adsorption and, as a mixed corrosion inhibitor, the charge transfer resistance of the system increases significantly and the capacitance value of the electrical double layer decreases significantly.
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来源期刊
Tenside Surfactants Detergents
Tenside Surfactants Detergents 工程技术-工程:化工
CiteScore
1.90
自引率
10.00%
发文量
57
审稿时长
3.8 months
期刊介绍: Tenside Surfactants Detergents offers the most recent results of research and development in all fields of surfactant chemistry, such as: synthesis, analysis, physicochemical properties, new types of surfactants, progress in production processes, application-related problems and environmental behavior. Since 1964 Tenside Surfactants Detergents offers strictly peer-reviewed, high-quality articles by renowned specialists around the world.
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