工业上可行的沸石膜去除六价铬的制备

Pub Date : 2023-01-01 DOI:10.1504/ijesd.2023.133822
R. Vinoth Kumar, Ashim Kumar Basumatary, G. Pugazhenthi
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引用次数: 0

摘要

本研究提出了在国产廉价管状陶瓷衬底上制备工业上可行的沸石膜。利用源材料,如氧化铝和二氧化硅,通过水热处理沉积在衬底上的一种沸石骨架,Faujasite。通过XRD、FESEM、zeta电位和接触角分析对膜进行了表征。沸石膜与陶瓷基板不同的物理和结构特征证实了复合膜的形成。此外,在交叉流系统的不同操作参数下,评估了膜去除合成废水中六价铬的潜力。在浓度为1000 ppm、压力为345 kPa、十字流速率为1.11 × 10-6 m3s-1的条件下,膜的最大除铬率为82%,通量为5.05 × 10-5 m3m-2s-1。该膜通过提供比其他膜更高的通量和更好的除铬效果,揭示了其重要的作用。
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Fabrication of industrially feasible zeolite membrane for the removal of hexavalent chromium
The present study proposed fabricating an industrially feasible zeolite membrane on an indigenously developed inexpensive tubular ceramic substrate. A type of zeolite framework, Faujasite, was deposited on the substrate using source materials, such as alumina and silica, by hydrothermal treatment. The membrane was characterised by XRD, FESEM, zeta potential, and contact angle analyses. Distinguishable physical and structural characteristics of the zeolite membrane from ceramic substrate substantiated a formation of the composite membrane. Further, the potentiality of the membrane was assessed on the removal of hexavalent chromium from synthetic wastewater at various operating parameters in a crossflow system. The prepared membrane offered a maximum chromium removal of 82% with a flux of 5.05 × 10-5 m3m-2s-1 at the operating conditions of 1,000 ppm concentration, 345 kPa pressure, and 1.11 × 10-6 m3s-1 crossflow rate. The membrane revealed its essential employment by providing a higher flux with better rejection than other membranes applied in chromium removal.
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