在不分离配体的情况下利用前体一步机械化学合成 3-EtO-salen 和 3-EtO-salophen Co(II) 和 Fe(III) 金属配合物

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2023-10-14 DOI:10.1007/s11243-023-00558-3

Getinet Tamiru Tigineh, Atakilt Abebe

{"title":"在不分离配体的情况下利用前体一步机械化学合成 3-EtO-salen 和 3-EtO-salophen Co(II) 和 Fe(III) 金属配合物","authors":"Getinet Tamiru Tigineh, Atakilt Abebe","doi":"10.1007/s11243-023-00558-3","DOIUrl":null,"url":null,"abstract":"<div><p>The work in this paper presents a one-pot mechanochemical synthesis of Co(II) and Fe(III) complexes of 3-EtO-salen and 3-EtO-salophen ligands without solvent and catalyst. The reaction was carried out by using ball mill technique starting with 3-ethoxysalicylaldehyde(<b>a</b>), 1,2-phenylenediamine(<b>b</b>), or ethylenediamine(<b>c</b>) and metal salts directly without isolating the ligand. Mechanochemical activation enables domino processes that do not require the isolation of the ligand and use of a solvent, in contrast to solution chemistry.</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanochemical synthesis of 3-EtO-salen and 3-EtO-salophen Co(II) and Fe(III) metal complexes from precursors in a single step without isolating the ligand\",\"authors\":\"Getinet Tamiru Tigineh, Atakilt Abebe\",\"doi\":\"10.1007/s11243-023-00558-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The work in this paper presents a one-pot mechanochemical synthesis of Co(II) and Fe(III) complexes of 3-EtO-salen and 3-EtO-salophen ligands without solvent and catalyst. The reaction was carried out by using ball mill technique starting with 3-ethoxysalicylaldehyde(<b>a</b>), 1,2-phenylenediamine(<b>b</b>), or ethylenediamine(<b>c</b>) and metal salts directly without isolating the ligand. Mechanochemical activation enables domino processes that do not require the isolation of the ligand and use of a solvent, in contrast to solution chemistry.</p></div>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2023-10-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11243-023-00558-3\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11243-023-00558-3","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

本文提出了一种无需溶剂和催化剂的单锅机械化学合成 3-EtO-水杨醛和 3-EtO-水杨酚配体的 Co(II) 和 Fe(III) 复合物的方法。该反应采用球磨技术，直接从 3-乙氧基水杨醛（a）、1,2-苯二胺（b）或乙二胺（c）和金属盐开始，无需分离配体。与溶液化学相比，机械化学活化可以实现多米诺过程，而无需分离配体和使用溶剂。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Mechanochemical synthesis of 3-EtO-salen and 3-EtO-salophen Co(II) and Fe(III) metal complexes from precursors in a single step without isolating the ligand

查看原文本刊更多论文

Mechanochemical synthesis of 3-EtO-salen and 3-EtO-salophen Co(II) and Fe(III) metal complexes from precursors in a single step without isolating the ligand

The work in this paper presents a one-pot mechanochemical synthesis of Co(II) and Fe(III) complexes of 3-EtO-salen and 3-EtO-salophen ligands without solvent and catalyst. The reaction was carried out by using ball mill technique starting with 3-ethoxysalicylaldehyde(a), 1,2-phenylenediamine(b), or ethylenediamine(c) and metal salts directly without isolating the ligand. Mechanochemical activation enables domino processes that do not require the isolation of the ligand and use of a solvent, in contrast to solution chemistry.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.