Vanja Radolić, Goran Šmit, Igor Miklavčić, Marina Poje Sovilj
{"title":"空气中赤铁矿粉与活性炭粉吸附氡的比较","authors":"Vanja Radolić, Goran Šmit, Igor Miklavčić, Marina Poje Sovilj","doi":"10.5562/cca4013","DOIUrl":null,"url":null,"abstract":": Adsorption of radon in the air was investigated on hematite, α -Fe 2 O 3 , and charcoal activated powder. Hematite had almost doubled efficiency in comparison to charcoal activated powder in the same experimental conditions but over a significantly longer per iod. Adsorption isotherms revealed a typical Langmuir shape on hematite and almost linear on activated charcoal. Linear models of Langmuir, Freundlich and Dubinin-Radushkevich isotherms showed that radon adsorption on both adsorbents is a favourable chemical process, with stronger interactions on hematite, that takes place forming a monolayer of ads orbed radon. The kinetic analysis confirmed forming of a monolayer on both adsorbents and two rate-controlling steps during radon adsorption on hematite, instead of one on activated charcoal, which could be considered as a reason of slower rate of process on hematite .","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparison of Radon Adsorption on Hematite and Charcoal Activated Powder in Air\",\"authors\":\"Vanja Radolić, Goran Šmit, Igor Miklavčić, Marina Poje Sovilj\",\"doi\":\"10.5562/cca4013\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": Adsorption of radon in the air was investigated on hematite, α -Fe 2 O 3 , and charcoal activated powder. Hematite had almost doubled efficiency in comparison to charcoal activated powder in the same experimental conditions but over a significantly longer per iod. Adsorption isotherms revealed a typical Langmuir shape on hematite and almost linear on activated charcoal. Linear models of Langmuir, Freundlich and Dubinin-Radushkevich isotherms showed that radon adsorption on both adsorbents is a favourable chemical process, with stronger interactions on hematite, that takes place forming a monolayer of ads orbed radon. The kinetic analysis confirmed forming of a monolayer on both adsorbents and two rate-controlling steps during radon adsorption on hematite, instead of one on activated charcoal, which could be considered as a reason of slower rate of process on hematite .\",\"PeriodicalId\":10822,\"journal\":{\"name\":\"Croatica Chemica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Croatica Chemica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.5562/cca4013\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Croatica Chemica Acta","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5562/cca4013","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Comparison of Radon Adsorption on Hematite and Charcoal Activated Powder in Air
: Adsorption of radon in the air was investigated on hematite, α -Fe 2 O 3 , and charcoal activated powder. Hematite had almost doubled efficiency in comparison to charcoal activated powder in the same experimental conditions but over a significantly longer per iod. Adsorption isotherms revealed a typical Langmuir shape on hematite and almost linear on activated charcoal. Linear models of Langmuir, Freundlich and Dubinin-Radushkevich isotherms showed that radon adsorption on both adsorbents is a favourable chemical process, with stronger interactions on hematite, that takes place forming a monolayer of ads orbed radon. The kinetic analysis confirmed forming of a monolayer on both adsorbents and two rate-controlling steps during radon adsorption on hematite, instead of one on activated charcoal, which could be considered as a reason of slower rate of process on hematite .
期刊介绍:
Croatica Chemica Acta (Croat. Chem. Acta, CCA), is an international journal of the Croatian Chemical Society publishing scientific articles of general interest to chemistry.