几种羧酸四乙基铵盐离子液体的合成

Muna Raad Mahmood, Mehdi Salih Shihab
{"title":"几种羧酸四乙基铵盐离子液体的合成","authors":"Muna Raad Mahmood, Mehdi Salih Shihab","doi":"10.22401/anjs.26.3.01","DOIUrl":null,"url":null,"abstract":"Some of organic ammonium salts, namely: 2-((4-carboxyphenyl) carbamoyl) benzoate tetraethylammonium, B1, 4-oxo-4-(pyridin-3-ylamino)-2-butenoate tetraethylammonium, B2, 2-((4-carbamoylphenyl) carbamoyl) benzoate tetraethylammonium, B3, 4-((4-carbamoylphenyl)amino)-4-oxobutanoate tetraethylammonium, B4, are successfully synthesized as ionic liquids. By spectral techniques of FTIR, 1H-NMR and 13C-NMR the structures of organic salts are confirmed. The thermal analysis by differential scanning calorimetry (DSC) has shown the thermal stability of the organic ammonium salts (B1-B4). A high conductivity characteristic as compared with that of NaCl has been detected in the aqueous solution.","PeriodicalId":7494,"journal":{"name":"Al-Nahrain Journal of Science","volume":"58 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Some Carboxylate Tetraethylammonium Salts as Ionic Liquids\",\"authors\":\"Muna Raad Mahmood, Mehdi Salih Shihab\",\"doi\":\"10.22401/anjs.26.3.01\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Some of organic ammonium salts, namely: 2-((4-carboxyphenyl) carbamoyl) benzoate tetraethylammonium, B1, 4-oxo-4-(pyridin-3-ylamino)-2-butenoate tetraethylammonium, B2, 2-((4-carbamoylphenyl) carbamoyl) benzoate tetraethylammonium, B3, 4-((4-carbamoylphenyl)amino)-4-oxobutanoate tetraethylammonium, B4, are successfully synthesized as ionic liquids. By spectral techniques of FTIR, 1H-NMR and 13C-NMR the structures of organic salts are confirmed. The thermal analysis by differential scanning calorimetry (DSC) has shown the thermal stability of the organic ammonium salts (B1-B4). A high conductivity characteristic as compared with that of NaCl has been detected in the aqueous solution.\",\"PeriodicalId\":7494,\"journal\":{\"name\":\"Al-Nahrain Journal of Science\",\"volume\":\"58 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Al-Nahrain Journal of Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22401/anjs.26.3.01\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Al-Nahrain Journal of Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22401/anjs.26.3.01","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

成功合成了2-(4-羧基苯基)氨甲酰苯甲酸四乙基铵、B1、4-氧-4-(吡啶-3-氨基)-2-丁酸四乙基铵、B2、2-((4-氨甲基苯基)氨甲酰苯甲酸四乙基铵、B3、4-((4-氨甲基苯基)氨基)-4-氧丁酸四乙基铵等有机铵盐离子液体。通过FTIR、1H-NMR和13C-NMR等光谱技术,确定了有机盐类的结构。差示扫描量热法(DSC)热分析表明了有机铵盐(B1-B4)的热稳定性。与NaCl相比,在水溶液中发现了高导电性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis of Some Carboxylate Tetraethylammonium Salts as Ionic Liquids
Some of organic ammonium salts, namely: 2-((4-carboxyphenyl) carbamoyl) benzoate tetraethylammonium, B1, 4-oxo-4-(pyridin-3-ylamino)-2-butenoate tetraethylammonium, B2, 2-((4-carbamoylphenyl) carbamoyl) benzoate tetraethylammonium, B3, 4-((4-carbamoylphenyl)amino)-4-oxobutanoate tetraethylammonium, B4, are successfully synthesized as ionic liquids. By spectral techniques of FTIR, 1H-NMR and 13C-NMR the structures of organic salts are confirmed. The thermal analysis by differential scanning calorimetry (DSC) has shown the thermal stability of the organic ammonium salts (B1-B4). A high conductivity characteristic as compared with that of NaCl has been detected in the aqueous solution.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信