{"title":"粘结剂含量对hmx基PBX烧退响应特性的影响研究","authors":"Bing-Xv Qiao, Zeng-You Liang, Tong-Tong Zhou, Hao-Qiang Gao, Xiao-Ru Ji, Chao-Hui Tong","doi":"10.1080/07370652.2023.2275203","DOIUrl":null,"url":null,"abstract":"ABSTRACTThe cook-off tests and numerical simulations were carried out on the HMX-based PBX to study the influence of binder content on the cook-off response characteristics of PBX. The temperature change history of the powder column was obtained, and the change in temperature due to crystal transformation was observed. The response temperature of the column was obtained. In addition, the results showed that the response temperature of the PBX decreased with the increase of the binder content. Under the same binder content, the damage to a slow cook-off bomb was higher than that of a fast cook-off bomb. In the fast cook-off test, the cook-off response temperature of the HMX-based PBX was 310.3 ℃~322.5 ℃ The critical Estane content when the response grade was combustion was 5%. Under the slow cook-off conditions, the response temperature was 260.8 ℃ ~278.6 ℃. The critical Estane content when the response grade was combustion was 7%. Numerical simulation results proved that adding binder would cause a temperature drop due to the crystal transformation. The higher the binder content, the more noticeable this phenomenon was. The maximum error between the numerical simulation and the test results did not exceed 6.5%. KEYWORDS: Binder contentcook-off testscrystal transformationHMX-based PBXnumerical simulation Disclosure StatementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors would like to acknowledge [Shanxi Science and Technology Department] grant number [20210302124210] to provide funds for conducting experiments.","PeriodicalId":15754,"journal":{"name":"Journal of Energetic Materials","volume":"39 3","pages":"0"},"PeriodicalIF":1.7000,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on the effect of binder content on the cook-off response characteristics of HMX-based PBX\",\"authors\":\"Bing-Xv Qiao, Zeng-You Liang, Tong-Tong Zhou, Hao-Qiang Gao, Xiao-Ru Ji, Chao-Hui Tong\",\"doi\":\"10.1080/07370652.2023.2275203\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACTThe cook-off tests and numerical simulations were carried out on the HMX-based PBX to study the influence of binder content on the cook-off response characteristics of PBX. The temperature change history of the powder column was obtained, and the change in temperature due to crystal transformation was observed. The response temperature of the column was obtained. In addition, the results showed that the response temperature of the PBX decreased with the increase of the binder content. Under the same binder content, the damage to a slow cook-off bomb was higher than that of a fast cook-off bomb. In the fast cook-off test, the cook-off response temperature of the HMX-based PBX was 310.3 ℃~322.5 ℃ The critical Estane content when the response grade was combustion was 5%. Under the slow cook-off conditions, the response temperature was 260.8 ℃ ~278.6 ℃. The critical Estane content when the response grade was combustion was 7%. Numerical simulation results proved that adding binder would cause a temperature drop due to the crystal transformation. The higher the binder content, the more noticeable this phenomenon was. The maximum error between the numerical simulation and the test results did not exceed 6.5%. KEYWORDS: Binder contentcook-off testscrystal transformationHMX-based PBXnumerical simulation Disclosure StatementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors would like to acknowledge [Shanxi Science and Technology Department] grant number [20210302124210] to provide funds for conducting experiments.\",\"PeriodicalId\":15754,\"journal\":{\"name\":\"Journal of Energetic Materials\",\"volume\":\"39 3\",\"pages\":\"0\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2023-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Energetic Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/07370652.2023.2275203\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Energetic Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/07370652.2023.2275203","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Study on the effect of binder content on the cook-off response characteristics of HMX-based PBX
ABSTRACTThe cook-off tests and numerical simulations were carried out on the HMX-based PBX to study the influence of binder content on the cook-off response characteristics of PBX. The temperature change history of the powder column was obtained, and the change in temperature due to crystal transformation was observed. The response temperature of the column was obtained. In addition, the results showed that the response temperature of the PBX decreased with the increase of the binder content. Under the same binder content, the damage to a slow cook-off bomb was higher than that of a fast cook-off bomb. In the fast cook-off test, the cook-off response temperature of the HMX-based PBX was 310.3 ℃~322.5 ℃ The critical Estane content when the response grade was combustion was 5%. Under the slow cook-off conditions, the response temperature was 260.8 ℃ ~278.6 ℃. The critical Estane content when the response grade was combustion was 7%. Numerical simulation results proved that adding binder would cause a temperature drop due to the crystal transformation. The higher the binder content, the more noticeable this phenomenon was. The maximum error between the numerical simulation and the test results did not exceed 6.5%. KEYWORDS: Binder contentcook-off testscrystal transformationHMX-based PBXnumerical simulation Disclosure StatementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors would like to acknowledge [Shanxi Science and Technology Department] grant number [20210302124210] to provide funds for conducting experiments.
期刊介绍:
The Journal of Energetic Materials fills the need for an international forum of scientific and technical interchange in the disciplines of explosives, propellants, and pyrotechnics. It is a refereed publication which is published quarterly. Molecular orbital calculations, synthetic and analytical chemistry, formulation, ignition and detonation properties, thermal decomposition, hazards testing, biotechnology, and toxicological and environmental aspects of energetic materials production are appropriate subjects for articles submitted to the Journal.